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Arsenide iodide

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Class of chemical compounds

Arsenide iodides or iodide arsenides are compounds containing anions composed of iodide (I) and arsenide (As). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide bromides, phosphide iodides, and antimonide iodides.

List

formula system space group unit cell Å volume density comment ref
Ca2AsI trigonal R3m a=4.397, c = 22.29, Z = 3 3.76 brown
Ca3AsI3 cubic I4132 a=12.42 3.99 colourless
Cu2P1.8As1.2I2 monoclinic P21/c a = 15.477, b = 13.200, c = 15.421, β = 115.406°, Z = 16 Cu exchangeable with Ag; band gap 1.2 eV
Ge38As8I8 cubic P43m a=10.611 metallic; water and air stable
Ag2P1.8As1.2I2 monoclinic P21/c a = 15.84, b = 13.68, c = 15.58 and β = 117.63° Z=16
Sn24As19.3I8 cubic a=22.179 Z=8 black
Sn20.5□3.5As22I8 cubic a=22.1837 low thermal conductivity
Sn24AsxP19.3−xI8 x=0-16 cubic Pm3n a = 10.9358—11.1495
Sn19.3Cu4.7As22I8 cubic Pm3n a = 11.1736 Z = 1 1394.4 6.236 clathrate; Zintl; diamagnetic
Sn24–x–δInxAs22–yI8 cubic Pm3n a = 11.088 (x = 0) to a = 11.343 (x = 10.7) clathrate
La2AsI2 trigonal P3m1 a=4.3795 c=10.910 5.56
Hg4AsI5 orthorhombic Cmca a=11.927 b=12.128 c=19.776 Z=8 2859.0 7.025 red
Hg4As2I3 cubic Pa3 a=12.999 Z=8 2196 8.06 black
HgI2⋅As4S4 monoclinic P21/c a=9.433 b=14.986 c=11.624 β=127.72° Z=4 1299 4.509 orange; dec 212 °C
Hg5AsS2I3 monoclinic C2/c a=13.339 b=8.444 c=13.428 β=118.352 Z=4 1331.2 7.599 black; dec 150 °C
Hg3AsSe4I hexagonal P63mc a = 7.6902, c = 9.968 Z=2 red; air stable
(AgI3)2 cubic Pa a = 13.138 Z = 4
(Hg2As)2(CdI4) monoclinic P21 a=7.945, b=12.934, c=8.094, β=116.898° 741.7
(SnI3) cubic P213 a = 13.110, Z = 4 2253.2 7.617 black

References

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  2. Hadenfeldt, C.; Herdejürgen, H. (February 1987). "Darstellung und Kristallstruktur der Calciumnitridhalogenide Ca2NCl und Ca2NBr". Zeitschrift für anorganische und allgemeine Chemie (in German). 545 (2): 177–183. doi:10.1002/zaac.19875450220. ISSN 0044-2313.
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  5. Jayasekera, Buddhimathie; Brock, Stephanie L. (2002). "Ag Ion-Exchange Reactions of Cu 2 P 3 I 2 and Cu 2 P 1.8 As 1.2 I 2". MRS Proceedings. 755: DD6.12. doi:10.1557/PROC-755-DD6.12. ISSN 0272-9172.
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  8. Kelm, E. A.; Zaikina, Yu. V.; Dikarev, E. V.; Shevelkov, A. V. (April 2009). "Distribution of phosphorus and arsenic atoms in the solid solution Sn24As x P19.3-x I8 with the structure of clathrate-I". Russian Chemical Bulletin. 58 (4): 746–750. doi:10.1007/s11172-009-0089-0. ISSN 1066-5285. S2CID 93897495.
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Arsenides
Binary arsenides
AsH3
+H 		He
LiAs Be BAs C +N +O F Ne
Na3As Mg AlAs -Si P S +Cl Ar
K CaAs Sc Ti V Cr MnAs Fe CoAs Ni Cu Zn3As2 GaAs -Ge As Se +Br Kr
Rb Sr YAs Zr Nb MoAs2 Tc Ru Rh PdAs2 Ag Cd3As2 InAs -Sn Sb +Te +I Xe
Cs Ba * Lu Hf TaAs WAs2 Re Os Ir Pt Au Hg Tl Pb BiAs Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
* La Ce PrAs Nd Pm SmAs Eu Gd Tb DyAs HoAs Er Tm Yb
** Ac Th Pa U NpAs
NpAs2 		PuAs Am Cm Bk Cf Es Fm Md No
Ternary arsenides
Quaternary arsenides
Quinary arsenides
See also
Salts and covalent derivatives of the iodide ion
HI
+H 		He
LiI BeI2 BI3
+BO3 		CI4
+C 		NI3
NH4I
+N 		I2O4
I2O5
I2O6
I4O9 		IF
IF3
IF5
IF7 		Ne
NaI MgI2 AlI
AlI3 		SiI4 PI3
P2I4
+P
PI5 		S2I2 ICl
ICl3 		Ar
KI CaI2 ScI3 TiI2
TiI3
TiI4 		VI2
VI3 		CrI2
CrI3
CrI4 		MnI2 FeI2
FeI3 		CoI2 NiI2
-Ni 		CuI ZnI2 GaI
GaI3 		GeI2
GeI4
+Ge 		AsI3
As2I4
+As 		Se IBr
IBr3 		Kr
RbI
RbI3 		SrI2 YI3 ZrI2
ZrI3
ZrI4 		NbI4
NbI5 		MoI2
MoI3 		TcI3 RuI3 RhI3 PdI2 AgI CdI2 InI
InI3 		SnI2
SnI4 		SbI3
+Sb 		TeI4
+Te 		I
I
3 		Xe
CsI
CsI3 		BaI2   LuI3 HfI3
HfI4 		TaI4
TaI5 		WI2
WI3
WI4 		ReI3
ReI
4 		OsI
OsI2
OsI3 		IrI3
IrI
4 		PtI2
PtI4 		AuI
AuI3 		Hg2I2
HgI2 		TlI
TlI3 		PbI2 BiI3 PoI2
PoI4 		AtI Rn
Fr RaI2   Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
LaI2
LaI3 		CeI2
CeI3 		PrI2
PrI3 		NdI2
NdI3 		PmI3 SmI2
SmI3 		EuI2
EuI3 		GdI2
GdI3 		TbI3 DyI2
DyI
3 		HoI3 ErI3 TmI2
TmI3 		YbI2
YbI3
AcI3 ThI2
ThI3
ThI4 		PaI4
PaI5 		UI3
UI4 		NpI3 PuI3 AmI2
AmI3 		CmI3 BkI
3 		CfI
2
CfI
3 		EsI2
EsI3 		Fm Md No
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