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Selenidogermanate

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Type of chemical compound

Selenidogermanates are compounds with anions with selenium bound to germanium. They are analogous with germanates, thiogermanates, and telluridogermanates.

List

name formula formula weight crystal

system

space

group

cell dimensions volume density comment ref
GeSe2
Ge4Se9 orthorhombic Pca21 a 17.8204 b 7.0029 c 12.0854
Li3Ge3Se6 triclinic P1 a 6.7728 b 8.6804 c 10.6300 α 74.519° β 76.334° γ 69.185°
·4.33H2O monoclinic P21 a=10.2246 b=20.4503 c=28.7242 β=97.850°
{Li4(thf)12}Ge4Se10 monoclinic C2/c a=24.845 b =12.692 c=25.625 β=119.00°
tetragonal I4 a=9.103 c =15.130
22Ge2Se6 monoclinic P21/n a 13.503 b 7.777 c 19.583 β 106.03°
(N2H5)4Ge2Se6 tetragonal I41cd a = 12.708 c = 21.955 Z = 8
22 triclinic P1 a = 7.805, b = 10.747, c = 11.445, α = 110.33°, β = 97.19°, γ = 92.62° V = 889.0
tetrakis(Tripropylammonium) hexakis(μ2-selenido)-tetrakis(selenoxo)-tetra-germanium(iv) monoclinic P21/c a 18.759 b 16.104 c 21.211 β 108.52°
(C2C1Im)4 1524.63 tetragonal P42/n a=13.675 c=12.042 Z=2 2251.9 2.249 yellowish
1-Ethyl-3-methyl-imidazolium (C2C1Im)6; 2747.96 triclinic P1 a=10.2607 b=17.6852 c=21.994 α=100.889

β= 95.600  γ=105.240 Z=2

3735.5 2.443 yellowish
(C2C1Im)6 2747.96 monoclinic P121/c1 a=22.206 b=9.544 c=36.823 β=105.37 Z=4 7524.8 2.426 yellow
(C2C1Im)8 4893.34 monoclinic C12/c1 a=20.527 b=28.744 c=19.720 β=94.640 Z=4 11597 2.803 yellow
2(C2C1Im)6 7340.01 monoclinic P121/n1 a=14.834 b=30.647 c=20.465 β=107.603 Z=2 8868 2.749 red
(C4C1im)2{} monoclinic P21/n a 9.9685 b 26.2588 c 13.9736 β 98.766°
Na2GeSe3 monoclinic P21/c a =7.097 b=16.068 c=6.073 β =113.69° Z=4 3.72 yellow
Na4GeSe4 orthorhombic Pnma a = 28.518 b=9.447 c=7.128 Z=8 orange-yellow
Na4 orthorhombic Cmcm a=13.507 b=13.363 c=11.034 Z=4 1881.6
Na4Ge(Se2)4 red
Na6Ge2Se6 monoclinic P21 a = 8.367 b = 11.924 c = 8.158 β = 118.6°
Na6Ge2Se7 monoclinic C2/c a=9.451 b=10.914 c=15.874 β=104.7° 3.51 yellow
Na8Ge4Se10 triclinic P1 a = 7.074 b = 8.098 c = 10.657 α = 73.4° β = 70.8° γ= 81.7°
Na8Ge4Se10 monoclinic P21/c a = 13.104 b=12.057 c=14.101 β= 92.9° Z=4 3.77 orange yellow
monoclinic C2 a = 12.862, b = 11.205, c = 8.141 Å, β = 107.40°
Na4Ge2Se6 · 16 H2O monoclinic P21/c a = 9.894 b = 11.781 c = 12.225 β = 92.90° Z = 2
Na6Ge2Se6 · 4 CH3OH
Na3GeSe3Br
Mg2GeSe4 437.05 orthorhombic Pnma a 13.50 b 7.85 c 6.37 Z=4 675 4.302 yellow
Li2MgGeSe4 orthorhombic Pmn21 a = 8.2961 b = 7.0069 c = 6.6116, Z = 2 384.33 3.686 yellow
Na4MgGe2Se6 735.21 monoclinic C2 a 7.722 b 11.994 c 7.096 β 106.66° Z=2 629.7 3.878 orange-yellow
K2GeSe4 monoclinic P21/c a=11.989 b=8.275 c=8.915 β=106.38° Z=4 848.8 3.65 orange
K2Ge4Se8 monoclinic P21/c a=7.3752 b=12.239 c=17.468 β=96.102°, Z=4 1156.8 band gap 1.8 eV
K4 cubic P43n a=13.1893
triclinic P1 a 7.8695 b 7.9576 c 12.314, α 80.24° β 87.66° γ 74.07°
monoclinic P21/c a 14.583 b 8.3858 c 14.17 β 96.27°
K6Ge2Se6 monoclinic C2/c a=9.076 b=12.851 c=8.480 β=116.76°
2 monoclinic P21/n a 8.733 b 13.432 c 13.583 β 91.486° Z=4 1592.8 2.256 red
2 monoclinic P21/n a 9.0574 b 14.209 c 13.1189° β 91.384° Z=4 1687.8 2.232 red
triclinic P1 a 9.448 b 10.178 c 10.436 α 109.090° β 104.169° γ 111.520° Z=1 802.7 2.271 brown
Na2MnGe2Se6 1439.72 tetragonal I4/mcm a = 7.772 c = 19.077 Z = 2 1152.3 4.150 @153K band gap 1.93 eV; brown
Na8Mn2(Ge2Se6)2 monoclinic C2 a 7.727 b 11.943 c 7.085 β 106.682° band gap 1.95 eV
K2MnGe2Se6 tetragonal I4/mcm a =8.1315 c =18.877
2Ge2Se6 monoclinic P21/n a 9.058 b 16.319 c 11.628 β 92.264°
(enH2)(Ge2Se7)2 orthorhombic Pbca a 15.816 b 13.638 c 24.677
2Ge2Se7 monoclinic P21/c a 16.489 b 14.524 c 15.860 β 101.03°
tetragonal I 41/a a=26.387 c 9.9435
tetragonal I4 a=8.988 c=15.49
Bis(trimethylammonium) decaselenidotetragermanatomanganate(II) 2 tetragonal I4 a 9.559 c 14.808
2Ge2Se6 monoclinic P21/n a 12.426 b 9.312 c 15.385 β 101.422°
tetragonal I 41/a a 26.285 c 9.882
K2FeGe3Se8 monoclinic P21 a 7.409 b 12.268 c 34.974 β 96.04° band gap 1.95 eV
2Ge2Se5(Se2) monoclinic P21/c a 15.741 b 14.463 c 16.390 β 103.03°
tetragonal I41/a a=26.001 c=9.708
triethylenetetramine 2Ge4Se10·0.5H2O monoclinic P21/c a 21.202 b 13.345 c 20.872 β 107.46°
(enH2)5·en cubic Pa3 a=a 20.8113 Z=12
6·0.25H2O Im3 a=22.43070
0.75Cu1.25GeSe3 tetragonal P421m a=12.9345 c 8.9057
decakis(1-ethyl-3-methyl-1H-imidazol-3-ium) hexakis(μ-cyanido)-nonatriacontakis(μ-selenido)-selenido-hepta-copper(i)-hexadeca-germanium(iv)-penta-sodium (C2C1Im)10 triclinic P1 a 19.2790 b 20.4268 c 23.2357 α 105.275° β 93.657° γ 115.206° Z=2 7822.6 2.610 red
decakis(1-ethyl-3-methyl-1H-imidazol-3-ium) hexakis(μ-cyanido)-nonatriacontakis(μ-selenido)-selenido-hepta-copper(i)-hexadeca-germanium(iv)-penta-sodium (C2C1Im)10 6147.36 triclinic P1 a 20.3454 b 20.8202 c 23.120 α 72.172° β 68.184° γ 60.802° Z=2 7842.1 2.472 red
1,2-dap = 1,2-diaminopropane monoclinic P21/c a 6.673 b 18.210 c 15.070 β 96.078°
monoclinic P21/c a 9.6327 b 20.6934 c 10.3704 β 100.646° band gap 1.69 eV
tren = tris(2-aminoethyl)amine 2∙2 orthorhombic P212121 a 9.8574 b 13.0311 c 32.77
2Ge2Se5(Se2) monoclinic P21/c a=15.741 b=14.463 c=16.390 β=103.03(3)°
{Ni(tepa)}2(μ-Ge2Se6) tetragonal I41/a a=26.001 c=9.7079
0.75Cu1.25GeSe3 tetragonal P421m a 12.9345 c 8.9057
Na2ZnGe2Se6 tetragonal I4/mcm a 7.757 c 18.734 band gap 2.36 eV
Cu2ZnGeSe4 tetragonal I4 band gap 1.38; air stable; SHG 43 pm/V at λ = 2900 nm
Cu4ZnGe2Se7 monoclinic C2 a 12.3443 b 5.6195 c 8.7904 β 98.693° band gap 0.91 eV; air stable
N-(2-aminoethyl)piperazine (H2NC4H8NCH2CH2NH2)(HNCH2CH2NH2)3Zn2Ge2Se8 orthorhombic P21212 a=18.928 b=30.849 c=6.3954
2Ga4Se8Ge4 monoclinic P21/c
NaGaGe3Se8 monoclinic P21/c a 7.233 b 11.889 c 17.550 β 101.75° Z=4 1477.5 4.235 orange
K2Ga2Ge2Se8 monoclinic P21/c a 7.3552 b 12.4151 c 17.6213 β 97.026° Z=4 1597.02 4.136 yellow
K3Ga3Ge7Se20 2413.79 monoclinic P21/c a 7.0520 b 39.033 c 6.9488 β 90.433° Z=2 1912.67 4.191 orange
K3Ga3(Ge4.95Si2.05)Se20 monoclinic Pc a 7.0101 b 38.928 c 6.9594 β 90.531°
Rb2GeSe4 559.4 monoclinic P2/m a=7.390 b=3.704 c=8.623 β=104.87 Z=1 228.1 4.07 orange-brown
Rb4Ge4Se10 monoclinic C2/c a = 16.095 b = 16.09 c = 9.390 β= 105.79°
Rb4Ge4Se12 orthorhombic Pna21 a 14.870 b 13.800 c 12.445 Z=4 2554 4.109 red
Rb4Ge4Se10 • CH3OH 1453.9 monoclinc C2 a=17.099 b=9.287 c=9.503 β=118.49 Z=2 1326.3 3.64 yellow
Rb2MnGe3Se8 orthorhombic P212121 a 7.2756 b 12.1668 c 16.8351
Rb2·3H2O tetragonal
Rb3(AlSe2)3(GeSe2)7 monoclinic P21/c a = 7.0580 b = 39.419 c = 7.0412 β = 90.360° Z = 2 #190K; band gap 2.4 eV
RbGaGeSe4 orthorhombic Pnma a=17.5750 b= 7.4718 c= 12.4449 Z=8 1634.23 4.419 colourless; air sensitive
γ-Sr2GeSe4 orthorhombic Ama2 a = 10.284 b = 10.543 c = 7.411 Z=4
Strontium Selenogermanate(III) Sr2Ge2Se5 monoclinic P21/n a=8.445 b=12.302 c=9.179 β=93.75° Z=4 Ge-Ge bond
tepa=tetraethylenepentamine (H2peha){2(μ-Ge2Se6)}Cl2 triclinic P1 a 9.1861 b 17.3698 c 19.5422 α 103.218° β 95.414° γ 101.439°
Y2(tepa)2(μ-OH)2(μ-Ge2Se6)]·H2O monoclinic C2/c a 21.87 b 12.245 c 18.724 β 127.58°
AgxNa(6-x)Ge2Se7 x=1.76
AgxNa(8-x)Ge4Se10 C2/c
K2Ag2GeSe4 orthorhombic Fddd a 6.613 b 13.776 c 21.822
Ag2FeGeSe4 orthorhombic
AgGaGeSe4 tetragonal I42d a = 5.8056 c = 10.349 348.81 band gap 2.27 eV
Rb2Ag2GeSe4 1579.76 orthorhombic Fddd a 6.5943 b 13.9740 c 22.627
RbAg3Ga8Se14 monoclinic Cm a 12.9155 b 11.7376 c 9.6693 β 116.367°
Ag2Sr3Ge2Se8 cubic I43d
Rb3·2H2O
Li7Cd4.5Ge4Se16 orthorhombic Pna21 a 14.165 b 8.2990 c 6.6869 band gap 2.18 eV; melt 985K
Na2CdGe2Se6 monoclinic Cc a 7.589 b 13.182 c 12.069 β 98.829° SHG 2×AgGaS2 at 2.09 μm
K2CdGe3Se8 1040.05 monoclinic P21 a=7.6069 b=12.4016 c=17.6585 β=95.306° Z=4 1658.71 4.165 brownish yellow
SrCdGeSe4 orthorhombic Ama2 a = 10.8245 b = 10.6912 c = 6.6792 Z=4 red; band gap 1.9 eV; melt 851; SHG 5× AgGaS2
2In4Se8Ge4 monoclinic P21/c a 7.642 b 12.470 c 18.222 β 95.214°
KInGeSe4 monoclinic P21/c a=7.6108 b=12.4473 c=18.0896 β=97.238° Z=8 1700.0 4.239 yellow
RbInGeSe4 orthorhombic Pnma a=17.9948 b=7.6908 c=12.6003 Z=8 1743.8 4.475 yellow
K3Ga3(Ge6.17Sn0.83)Se20 monoclinic Pc a 7.0843 b 39.404 c 7.0212 β 90.567°
Na9Sb(Ge2Se6)2 monoclinic C2/c a = 8.95 b = 24.33 c = 7.066 β = 122.10° Z=2 1303 3.992 red
Sr3GeSb2Se8 orthorhombic Pnma a = 12.633 b = 4.301 c = 28.693 Z = 4 1558.8 band gap 0.75 eV
Cs4Ge2Se6 monoclinic P21/n a 7.6295 b 9.6884 c 19.773 β=98.78°
Cs4Ge2Se8 1308.5 monoclinic C2 a=17.503 b=9.549 c=9.751 β=118.16° Z=2 1436.8 3.87 orange-yellow
Cs4Ge4Se10 monoclinic C2/c a = 16.348 b = 16.49 c = 9.771 β = 107.10°
Cs4Ge4Se10 · 2CH3OH 1675.7 monoclinic C2/m a=15.278 b=7.624 c=10.090 β=121.71° Z=2 999.8 4.34 yellow
Cs4Ge4Se12 1769.52 orthorhombic Pna21 a 15.193 b 13.944 c 12.845 Z=4 2721.4 4.319 red
(C4C1C1im)7{} cubic P43m a=15.446 Cs in a tetrahedron
heptakis(1-ethyl-3-methyl-1H-imidazol-3-ium) hexatriacontakis(μ-selenido)-tetraselenido-cesium-tetra-germanium(ii)-hexadeca-germanium(iv) (C2C1Im)7 4831.2 orthorhombic P212121 a 18.1595 b 18.5017 c 36.632 Z=4 12307.8 2.980 yellow
Cs2MgGe3Se8 orthorhombic P212121 a 7.6635 b 12.7242 c 17.7724
Cs 693.57 monoclinic P21/n a=11.3115 b=12.3519 c=11.4514 β =93.359 Z=4 1597.2 2.884 black
Cs2MnGe3Se8 orthorhombic P212121 a 7.6376 b 12.648 c 17.762
Cs2·3H2O tetragonal
Cs2Cu2GeSe4 monoclinic C2/c a 7.8231 b 23.953 c 6.0197 β 113.75°
Cs2ZnGe3Se8 orthorhombic P212121 a 7.5756 b 12.6191 c 17.6543
CsGaGeSe4 orthorhombic Pnma a= 17.7666 b= 7.5171 c= 12.6383 Z=8 1687.9 4.652 colourless
Cs2Ge3Ga6Se14 P3m1 a = 7.6396 c =13.5866 Z = 1 686.72 dark red
(Cs6Cl)2Cs5 tetragonal I4/m a 14.3870 c 28.012
band gap 2.89 eV; porous layers
(Cs6Br)2Cs5 tetragonal I4/m a 14.3806 c 27.934
(Cs6I0.6Cl0.5)2Cs5 tetragonal I4/m a 14.4267 c 28.082
(Cs5KCl)2Cs5 tetragonal I4/m a=14.3309 c=27.797
(Rb6Cl)2Cs5 tetragonal I4/m a=14.2193 c=27.410 Z=2 5542
(Rb6Br)2Cs5 tetragonal I4/m a=14.4034 c=27.598 Z=2 5646.3
Cs3AsGeSe5 monoclinic C2/m a 14.252 b 7.4 c 10.335 β 124.07°
CsAg3Ga8Se14 monoclinic Cm a 12.9694 b 11.7931 c 9.7011 β 116.805°
Cs3·2H2O
Cs2CdGe3Se8 orthorhombic P212121 7.7048 b 12.6822 c 17.8208
Cs2Ge3In6Se14 R3m a = 7.9951 c = 41.726 band gap 2.08 eV
Ba2Ge2Se5 orthorhombic Pnma a=12.594 b=9.174 c=9.160 Z=4
825.25 orthorhombic Pbca a 13.916 b 15.097 c 16.116 Z=8 3385.9 3.238 light yellow
Ba6Ge2Se12 monoclinic P21/c a = 10.0903 b = 9.3640 c = 25.7643 β = 90.303°
Ba7Ge2Se17 orthorhombic Pnma a = 12.652 b = 20.069 c = 12.3067
Ba4Ge3Se9Cl2 P63 a 10.0924 b 10.0924 c 12.512
Ba3·19H2O 2716.66 triclinic P1 a 12.184 b 15.089 c 15.868 α 88.73° β 73.68° γ 71.06° Z=2 2640.4 3.412 red
Ba3·30H2O rhombohedral R3c a 20.463 c 25.11 Z=6 9109 3.188 orange-red
BaCu2GeSe4 P3121 a 6.5014 c 16.266 red
BaZnGeSe4 orthorhombic Ama2 a = 11.3255 b = 11.2527 c = 6.2917 band gap 2.46 eV
LiBa4Ga5Se12 orthorhombic P421c a 13.0056 b 13.0056 c 6.2671 band gap 2.44 eV
Ba4Ge3Se9Br2 hexagonal P63 a = 10.2345 c = 12.5306
BaCdGeSe4 orthorhombic Fdd2 a=22.167 b=22.768 c=13.303 band gap 1.67 eV; SHG 0.5 × AgGaS2
Ba4GeSb2Se11 1734.01 orthorhombic Cmc21 a = 9.37 b = 25.85, c = 8.80 Z=4 2131 5.404
La4Ge3Se2S10 rhombohedral R3c a=19.5575 c=8.1468 2698.6 4.605 Yellow-orange
La4Ge3Se4S8 rhombohedral R3c 2745.3 Yellow-orange
La4Ge3Se6S6 rhombohedral R3c 2792.6 orange
La4Ge3Se8S4 rhombohedral R3c 2845.3 red
La4Ge3Se10S2 rhombohedral R3c 2912.1 red
lanthanum(III) bis Na9La2 monoclinic C12/m1 a =7.974 b=12.337 c=7.114 β=107.101° Ζ=1 669.0 orange
Ba4LaSbGe3Se13 monoclinic P21/c a=16.3330 b=12.5115 c=13.0321 β=103.457° Z=4 2590.0 red; band gap 2.0 eV
[Ce4(tepa)4(μ-GeSe4)(μ-GeSe5)(μ-Ge2Se6) triclinic P1 a 12.273 b 16.624 c 18.281 α 91.264° β 101.034° γ 96.497°
KCeGeSe4 monoclinic P21 a = 6.852 b = 7.025 c = 9.017 β = 108.116° Z = 2
Pr(teta)(tren)Cl]2(en) triclinic P1 a 10.3153 b 10.4707 c 14.0511 α 99.606° β 92.679° γ 119.146°
Nd(teta)(tren)Cl]2(en) triclinic P1 a 10.2840 b 10.4774 c 14.0341 α 99.655° β 92.651° γ 119.161°
Na9Sm(Ge2Se6)2 monoclinic C2/m a = 7.916 b = 12.244 c = 7.105 β = 106.99° Z = 1 658.6
Sm2(μ-OH)2(tepa)2(μ-Ge2Se6) monoclinic P21/n a 12.10 b 11.41 c 12.71 β 92.81°
Sm(teta)(tren)Cl]2(en) triclinic P1 a 10.3327 b 10.482 c 14.003 α 77.816° β 87.499° γ 60.62°
NaSmGeSe4·0.25Na2Se monoclinic C2/c a 22.508 b 11.0307 c 6.8261 β 103.038°
KSmGeSe4 monoclinic P21 a = 6.774 b = 6.994 c = 8.960 β = 108.225° Z = 2 403.2
RbSmGeSe4 orthorhombic P212121 a = 6.7347 b = 7.0185 c = 17.723 Z=4 837.7
CsSmGeSe orthorhombic P212121 a=6.707 b=7.067 c=18.334 Z=4 869.1
Eu2GeSe4 monoclinic P21 a = 6.964 b = 7.055 c = 8.400 β = 108.12° Z = 2 deep red
Eu2GeSe4 monoclinic P21/m a = 6.969 b = 7.059 c = 8.516 β = 107.99° Z = 2 @673K
Eu2Ge2Se5 monoclinic P21/n a = 8.421 b = 12.235 c = 9.127 β = 93.67° Z = 4 deep red
{Eu(en)3}2(μ-OH)2]Ge2Se6 monoclinic P21/n a 10.062 b 11.538 c 15.227 β 98.470°
Eu(teta)(tren)Cl]2(en) triclinic P1 a 10.364 b 10.549 c 14.1157 α 77.299° β 87.606° γ 60.697°
{Eu(tepa)(μ-OH)}2(μ-Ge2Se8) monoclinic P21/n a 12.384 b 11.697 c 12.965 β 94.107°
Na2EuGeSe4 cubic I43m a=7.3466 Z=2
Na0.75Eu1.625GeSe4 cubic I43d a=14.7065 Z=16
K2EuGeSe5 monoclinic P21/c a = 11.8056 b = 9.9630 c = 8.9456 β = 91.195° Z = 4 1051.9 4.404 @167K; band gap 1.84 eV; Eu(II)
EuCdGeSe4 orthorhombic Ama2 a 10.7525 b 10.6275 c 6.6740 Z=4 762.6 5.685 red; band gap 2.25 eV; SHG 3.8 × AgGaS2
Gd(teta)(tren)Cl]2(en) triclinic P1 a 10.310 b 10.495 c 14.055 α 77.50° β 87.51° γ 60.81°
{Gd(tepa)(μ-OH)}2(μ-Ge2Se8) monoclinic P21/n a 12.316 b 11.667 c 12.868 β 93.70°
{Dy(tepa)(μ-OH)}2(μ-Ge2Se8) monoclinic P21/n a 12.329 b 11.627 c 12.882 β 94.177°
Ge2Se6 a 10.026 b 11.526 c 15.147 β 99.030°
Tb2(tepa)2(μ-OH)2(μ-Ge2Se8) monoclinic P21/n a 12.228 b 11.587 c 12.782 β 93.458°
Tb(teta)(tren)Cl]2(en) triclinic P1 a 10.2303 b 10.4499 c 14.0083 α 99.655° β 92.737° γ 119.069°
·0.5H2O monoclinic C2/c a 22.007 b 12.3363 c 18.2590 β 125.196°
Ge2Se6 monoclinic P21/n a 9.997 b 11.550 c 15.109 β 99.289°
Ge2Se6 monoclinic P21/n a 11.920 b 11.583 c 13.691 β 98.154°
Ho2(μ-OH)2(tepa)2(μ-Ge2Se6) orthorhombic Pbca a 12.1791 b 13.487 c 20.346
(H2peha){2(μ-Ge2Se6)}Cl2 triclinic P1 a 9.1544 b 17.382 c 19.443, α 102.994° β 95.306° γ 101.406°
(H3O) orthorhombic Pccn a 13.7846 b 14.3998 c 17.9221
Tm2(tepa)2(μ-OH)2(μ-Ge2Se6) orthorhombic Pbca a 12.1702 b 13.528 c 20.281
Li2HgGeSe4 602.90 orthorhombic Pna21 a=14.150 b=8.260 c=6.692 Z=4 782.2 5.119 yellow
Na2Hg3Ge2Se8 1424.61 tetragonal P4c2 a=9.1938 c=9.5437 Z=2 806.69 5.865 red
SrHgGeSe4 orthorhombic Ama2 a 10.8375 b 10.7456 c 6.6377 NLO 5 × AgGaS2
BaHgGeSe4 orthorhombic Ama2 a 11.255 b 11.033 c 6.685 NLO 5 × AgGaS2
EuHgGeSe4 orthorhombic Ama2 a 10.6530 b 10.5990 c 6.5986 band gap; SHG 3.1 × AgGaS2
TlGaGeSe4 orthorhombic Pnma a= 17.4742 b= 7.4105 c= 11.9406 Z=8 1546.22 5.692 red
Tl2Ga2GeSe6 tetragonal I4/mmc a = 8.0770 c = 6.2572 Z = 4
TlInGeSe4 702 monoclinic P21/c a= 7.586 b= 12.134 c=18.023 β= 96.037° Z=8 1649.8 5.653 yellow
TlInGe2Se6 trigonal R3 a = 10.1798 c = 9.2872 band gap 2.38 eV
α-Pb2GeSe4
Na0.5Pb1.75GeSe4 cubic I43d a = 14.662
PbGa2GeSe6 melt 687 °C; phase transition 522 °C
Pb4Ga4GeSe12
Pb3Ga2GeSe8 P421c melt incongruently 656 °C
Sr1.31Pb0.69GeSe4 orthorhombic Ama2 a = 10.31220 b = 10.39320 c = 7.42140
Sr0.19Pb1.81GeSe4 I42d a = 14.6177
Sr12.6Pb6.4Ge11Se44 hexagonal P63 a = 19.9867 c = 12.0546 4170.28 black; band gap 1.8 eV
Ag0.5Pb1.75GeS3Se band gap 2.0 eV

References

  1. ^ Wu, Zhou; Nußbruch, Isabell; Nier, Simon; Dehnen, Stefanie (23 December 2021). "Ionothermal Access to Defined Oligomers of Supertetrahedral Selenido Germanate Clusters". JACS Au. 2 (1): 204–213. doi:10.1021/jacsau.1c00473. PMC 8790736. PMID 35098237.
  2. ^ Fjellvåg, Helmer; Kongshaug, Kjell Ove; Stølen, Svein (2001). "Crystal structure of Ge4Se9: a new germanium selenide with Se2 pairs breaking the edge-sharing GeSe4 tetrahedra in GeSe2". Journal of the Chemical Society, Dalton Transactions (7): 1043–1045. doi:10.1039/b009794m.
  3. Li, Guangmao; Zhen, Ni; Chu, Yu; Zhou, Zhongxiang (2017). "Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters". Dalton Transactions. 46 (47): 16399–16403. doi:10.1039/C7DT03781C. ISSN 1477-9226. PMID 29134215.
  4. ^ Duchardt, Marc; Haddadpour, Sima; Kaib, Thomas; Bron, Philipp; Roling, Bernhard; Dehnen, Stefanie (2021-04-05). "Different Chemical Environments of [Ge 4 Se 10 ] 4– in the Li + Compounds [Li 4 (H 2 O) 16 ][Ge 4 Se 10 ]·4.33H 2 O, [{Li 4 (thf) 12 }Ge 4 Se 10 ], and [Li 2 (H 2 O) 8 ][MnGe 4 Se 10 ], and Ionic Conductivity of Underlying "Li 4 Ge 4 Se 10 "". Inorganic Chemistry. 60 (7): 5224–5231. doi:10.1021/acs.inorgchem.1c00225. ISSN 0020-1669. PMID 33764781. S2CID 232366801.
  5. ^ Liu, Shuzhen; Sun, Peipei; Han, Jingyu; Liu, Yun; Shen, Yali; Tang, Chunying; Sun, Hui; Jia, Dingxian (February 2017). "Solvothermal syntheses, crystal structures, optical and thermal properties of new selenidogermanate and polyselenidogermanate". Journal of Chemical Sciences. 129 (2): 167–175. doi:10.1007/s12039-017-1224-3. ISSN 0974-3626. S2CID 99258976.
  6. Mitzi, David B. (2005-05-01). "Synthesis, Structure, and Thermal Properties of Soluble Hydrazinium Germanium(IV) and Tin(IV) Selenide Salts". Inorganic Chemistry. 44 (10): 3755–3761. doi:10.1021/ic048276l. ISSN 0020-1669. PMID 15877460.
  7. Park, Chang-Woo; Pell, Michael A.; Ibers, James A. (1996-01-01). "Electrochemical Synthesis of [NEt 4 ] 2 [enH] 2 [Ge 2 Se 6 ] and [NEt 4 ] 4 [Sn 4 Se 10 ]". Inorganic Chemistry. 35 (16): 4555–4558. doi:10.1021/ic9514859. ISSN 0020-1669.
  8. Blachnik, R.; Fehlker, A. (2000-01-01). "Crystal structure of tetrakis(tripropylammonium) decaselenidotetragermanate(IV), [C9H21NH]4[Ge4Se10]". Zeitschrift für Kristallographie - New Crystal Structures. 215 (1): 95–97. doi:10.1515/ncrs-2000-0150. ISSN 2197-4578. S2CID 95268481.
  9. ^ {{Cite journal |last1=Santner |first1=Silke |last2=Wolff |first2=Alexander |last3=Ruck |first3=Michael |last4=Dehnen |first4=Stefanie |date=2018-08-14 |title=Multi-Valent Group 14 Chalcogenide Architectures from Ionic Liquids: 0D-{ 7− } and 2D-{ 2− } |url=https://onlinelibrary.wiley.com/doi/10.1002/chem.201802199 |journal=Chemistry: A European Journal|language=en |volume=24 |issue=46 |pages=11899–11903 |doi=10.1002/chem.201802199 |pmid=29806888 |s2cid=44064145 |issn=0947-6539}}
  10. ^ Eisenmann, Brigitte; Hansa, Jendy; Schafer, Herbert (1985-04-01). "Zur Kenntnis der Selenidosilikate und -germanate Na 4 Si 4 Se 10 , Na 2 GeSe 3 und Na 8 Ge 4 Se 10 / On the Selenidosilicates and Germanates Na 4 Si 4 Se 10 , Na 2 GeSe 3 and Na 8 Ge 4 Se 10". Zeitschrift für Naturforschung B. 40 (4): 450–457. doi:10.1515/znb-1985-0402. ISSN 1865-7117. S2CID 97026108.
  11. Klepp, Kurt O. (1985-07-01). "Darstellung und Kristallstruktur von Na 4 GeSe 4 : Ein neues ortho-Selenogermanat(IV)". Zeitschrift für Naturforschung B. 40 (7): 878–882. doi:10.1515/znb-1985-0705. ISSN 1865-7117. S2CID 98125379.
  12. Eisenmann, B.; Hansa, J. (1993-02-01). Eisenmann, B.; Hansa, J. (eds.). "Crystal structure of tetrasodium decaselenotetragermanate, Na 4 [Ge 4 Se 10 ]". Zeitschrift für Kristallographie - Crystalline Materials. 205 (2): 325–326. Bibcode:1993ZK....205..325E. doi:10.1524/zkri.1993.205.Part-2.325. ISSN 2194-4946. S2CID 101618869.
  13. Feltz, A.; Pfaff, G. (January 1985). "Glass formation and properties of chalcogenide systems XXXIV. Na4Ge(Se2)4 as a model compound for the short range order of vitreous GeSe4". Journal of Non-Crystalline Solids. 69 (2–3): 425–428. Bibcode:1985JNCS...69..425F. doi:10.1016/0022-3093(85)90044-4.
  14. ^ Eisenmann, B.; Hansa, J.; Schäfer, u.H. (November 1985). "Oligoselenidogermanate (III): Zur kenntnis von Na6Ge2Se6 und Na8Ge4Se10". Materials Research Bulletin (in German). 20 (11): 1339–1346. doi:10.1016/0025-5408(85)90127-8.
  15. EISENMANN, B; HANSA, J.; SCHÄFER, H. (1986). "Na6Ge2Se7, das erste selenidogermanat(IV)". Na6Ge2Se7, das Erste Selenidogermanat(IV). 23 (1): 8–13. ISSN 0035-1032.
  16. Villars, Pierre; Cenzual, Karin; Gladyshevskii, Roman (2017-07-24). Handbook of Inorganic Substances 2017. Walter de Gruyter GmbH & Co KG. ISBN 978-3-11-043655-6.
  17. Krebs, B.; Jacobsen, H.-J. (March 1976). "Darstellung und Struktur von Na4GeSe4 • 14H2O". Zeitschrift für anorganische und allgemeine Chemie (in German). 421 (2): 97–104. doi:10.1002/zaac.19764210202. ISSN 0044-2313.
  18. Krebs, Bernt; Müller, Herbert (January 1983). "Selenogermanate aus wäßriger Lösung: Darstellung und Struktur von Na4Ge2Se6 · 16 H2O". Zeitschrift für anorganische und allgemeine Chemie (in German). 496 (1): 47–57. doi:10.1002/zaac.19834960106. ISSN 0044-2313.
  19. Feltz, A.; Pfaff, G. (July 1978). "Über Glasbildung und Eigenschaften von Chalkogenidsystemen. XIII. Über die Verbindungen Na6Ge2S6 · 4 CH3OH und Na6Ge2Se6 · 4 CH3OH". Zeitschrift für anorganische und allgemeine Chemie (in German). 442 (1): 41–48. doi:10.1002/zaac.19784420106. ISSN 0044-2313.
  20. Feltz, A.; Pfaff, Gerhard (August 1980). "Über Glasbildung und Eigenschaften von Chalkogenidsystemen. XXI [1]. Über Na3GeS3Br und Na3GeSe3Br und die amorphen Verbindungen Ge2S3 und Ge2Se3". Zeitschrift für anorganische und allgemeine Chemie (in German). 467 (1): 211–217. doi:10.1002/zaac.19804670124. ISSN 0044-2313.
  21. Wu, Kui; Su, Xin; Yang, Zhihua; Pan, Shilie (2015). "An investigation of new infrared nonlinear optical material: BaCdSnSe 4 , and three new related centrosymmetric compounds: Ba 2 SnSe 4 , Mg 2 GeSe 4 , and Ba 2 Ge 2 S 6". Dalton Transactions. 44 (46): 19856–19864. doi:10.1039/C5DT03215F. ISSN 1477-9226. PMID 26509847.
  22. Gao, Hongbo; Zhang, Kewang; Abudurusuli, Ailijiang; Bai, Chen; Yang, Zhihua; Lai, Kangrong; Li, Junjie; Pan, Shilie (2021-10-18). "Syntheses, Structures and Properties of Alkali and Alkaline Earth Metal Diamond-Like Compounds Li2MgMSe4 (M = Ge, Sn)". Materials. 14 (20): 6166. Bibcode:2021Mate...14.6166G. doi:10.3390/ma14206166. ISSN 1996-1944. PMC 8537313. PMID 34683761.
  23. Wu, Kui; Yang, Zhihua; Pan, Shilie (2015-11-02). "Na 4 MgM 2 Se 6 (M = Si, Ge): The First Noncentrosymmetric Compounds with Special Ethane-like [M 2 Se 6 ] 6– Units Exhibiting Large Laser-Damage Thresholds". Inorganic Chemistry. 54 (21): 10108–10110. doi:10.1021/acs.inorgchem.5b01859. ISSN 0020-1669. PMID 26484949.
  24. ^ Sheldrick, W. S.; Schaaf, B. (1995-10-01). "Methanolothermale Synthese und Kristallstruktur von Diselenido- und Ditelluridogermanaten(IV) der Alkalimetalle K – Cs / M ethanolothermal Synthesis and Crystal Structure of Diselenido- and Ditelluridogerm anates(IV) of the Alkali Metals K – Cs". Zeitschrift für Naturforschung B. 50 (10): 1469–1475. doi:10.1515/znb-1995-1007. ISSN 1865-7117. S2CID 97624411.
  25. Gui-Hua, Wang; Yong-Ge, W. E. I.; Gui-Ming, S. H. U.; Li-Dan, Zhang; Hong-You, G. U. O.; Ping, Wang (2004-01-28). "Solid State Synthesis, Crystal Structure and Reflectance Spectra of K2Ge4Se8". Acta Chimica Sinica. 62 (2): 165. ISSN 0567-7351.
  26. ^ Melullis, Maike; Dehnen, Stefanie (October 2007). "Syntheses, Crystal Structures, UV-Vis Spectra and First NMR Spectra of New Potassium Salts of Chalcogenogermanates". Zeitschrift für anorganische und allgemeine Chemie (in German). 633 (13–14): 2159–2167. doi:10.1002/zaac.200700311.
  27. B., Eisenmann; E., Kieselbach; H., Schaefer; H., Schrod (1984). "On thio-, selenido-, and telluridogermanates(III): K6Ge2S6, K6Ge2Se6, and Na6Ge2Te6". Zeitschrift für anorganische und allgemeine Chemie (in German). 516 p. 49-54. ISSN 0044-2313.
  28. ^ Luo, Hai-Ying; Zhou, Jian; Cao, Shumei (2019). "A series of new hybrid chalcogenogermanates: the rare examples of chalcogenogermanates combined with trivalent vanadium complexes". Dalton Transactions. 48 (29): 10907–10914. doi:10.1039/C9DT02077B. ISSN 1477-9226. PMID 31282904. S2CID 195828996.
  29. Zhou, Molin; Yin, Wenlong; Liang, Fei; Mar, Arthur; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2016). "Na 2 MnGe 2 Se 6 : a new Mn-based antiferromagnetic chalcogenide with large Mn⋯Mn separation". Journal of Materials Chemistry C. 4 (46): 10812–10819. doi:10.1039/C6TC03825E. ISSN 2050-7526.
  30. Balijapelly, Srikanth; Craig, Andrew J.; Bin Cho, Jeong; Jang, Joon I.; Ghosh, Kartik; Aitken, Jennifer A.; Chernatynskiy, Aleksandr V.; Choudhury, Amitava (April 2022). "Building-block approach to the discovery of Na8Mn2(Ge2Se6)2: A polar chalcogenide exhibiting promising harmonic generation signals with a high laser-induced damage threshold". Journal of Alloys and Compounds. 900: 163392. doi:10.1016/j.jallcom.2021.163392. S2CID 245466958.
  31. Li, Zhuang; Liu, Youquan; Zhang, Shengzi; Xing, Wenhao; Yin, Wenlong; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2020-06-01). "Functional Chalcogenide Na 2 HgSn 2 Se 6 and K 2 MnGe 2 Se 6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability". Inorganic Chemistry. 59 (11): 7614–7621. doi:10.1021/acs.inorgchem.0c00490. ISSN 0020-1669. PMID 32412240. S2CID 218647656.
  32. ^ Jia, Dingxian; Zhu, Aimei; Zhang, Yong; Deng, Jie (March 2007). "New Selenidogermanates with Transition-Metal Complexes as Counterions: Solvothermal Synthesis, Crystal Structures, and Properties of [Mn(en)3]2Ge2Se6 and [Fe(dien)2]2Ge2Se6". Monatshefte für Chemie - Chemical Monthly. 138 (3): 191–197. doi:10.1007/s00706-007-0596-3. ISSN 0026-9247. S2CID 95254867.
  33. ^ van Almsick, Tobias; Loose, Anja; Sheldrick, William S. (January 2005). "Solvothermal Synthesis and Structure of the [Ge2Se7]4? Anion in (enH2)[{Mn(en)2(enH)}2(?-en)](Ge2Se7)2 and [Mn(dien)2]2Ge2Se7". Zeitschrift für anorganische und allgemeine Chemie (in German). 631 (1): 21–23. doi:10.1002/zaac.200400409. ISSN 0044-2313.
  34. ^ Chen, Jiang-Fang; Jin, Qin-Yan; Pan, Ying-Li; Zhang, Yong; Jia, Ding-Xian (January 2010). "Solvothermal Syntheses and Characterization of New Transition Metal Chalcogenidogermanates [{Co(tepa)} 2 (μ-Ge 2 S 6 )] and [{M(tepa)} 2 (μ-Ge 2 Se 6 )] (M = Mn, Fe) (tepa = Tetraethylenepentamine)". Zeitschrift für anorganische und allgemeine Chemie. 636 (1): 230–235. doi:10.1002/zaac.200900141.
  35. Haddadpour, Sima; Melullis, Maike; Staesche, Halgard; Mariappan, C. R.; Roling, Bernhard; Clérac, Rodolphe; Dehnen, Stefanie (2009-02-16). "Inorganic Frameworks from Selenidotetrelate Anions [T 2 Se 6 ] 4− (T = Ge, Sn): Synthesis, Structures, and Ionic Conductivity of [K 2 (H 2 O) 3 ][MnGe 4 Se 10 ] and (NMe 4 ) 2 [MSn 4 Se 10 ] (M = Mn, Fe)". Inorganic Chemistry. 48 (4): 1689–1698. doi:10.1021/ic802170f. ISSN 0020-1669. PMID 19159241.
  36. Van Almsick, Tobias; Sheldrick, William S. (2005-11-15). "Bis(trimethylammonium) decaselenidotetragermanatomanganate(II)". Acta Crystallographica Section E: Structure Reports Online. 61 (11): m2348 – m2350. doi:10.1107/S1600536805032770. ISSN 1600-5368.
  37. Feng, Kai; Wang, Wendong; He, Ran; Kang, Lei; Yin, Wenlong; Lin, Zheshuai; Yao, Jiyong; Shi, Youguo; Wu, Yicheng (2013-02-18). "K 2 FeGe 3 Se 8 : A New Antiferromagnetic Iron Selenide". Inorganic Chemistry. 52 (4): 2022–2028. doi:10.1021/ic302394e. ISSN 0020-1669. PMID 23356497.
  38. Zhang, Feng; Yin, Xian-Hong; Liu, Xing; Zhou, Jian (August 2011). "Two Novel Adamantane-Like Thio/Selenidogermanates with Complex Cations". Zeitschrift für anorganische und allgemeine Chemie. 637 (10): 1388–1393. doi:10.1002/zaac.201100106.
  39. ^ Wang, Yu-Long; Zhang, Bo; Li, Wei-An; Feng, Mei-Ling; Huang, Xiao-Ying (November 2017). "Two new 3D heterometallic chalcogenides based on copper-rich selenogermanate clusters". Inorganic Chemistry Communications. 85: 41–44. doi:10.1016/j.inoche.2017.05.023.
  40. ^ Liu, Hua-Wei; Wang, Kai-Yao; Ding, Dong; Sun, Meng; Cheng, Lin; Wang, Cheng (2019). "Deep eutectic solvothermal synthesis of an open framework copper selenidogermanate with pH-resistant Cs + ion exchange properties". Chemical Communications. 55 (92): 13884–13887. doi:10.1039/C9CC06906B. ISSN 1359-7345. PMID 31675017. S2CID 207815079.
  41. ^ Wu, Zhou; Weigend, Florian; Fenske, Dieter; Naumann, Tim; Gottfried, J. Michael; Dehnen, Stefanie (2023-02-15). "Ion-Selective Assembly of Supertetrahedral Selenido Germanate Clusters for Alkali Metal Ion Capture and Separation". Journal of the American Chemical Society. 145 (6): 3802–3811. doi:10.1021/jacs.2c13523. ISSN 0002-7863. PMC 9936546. PMID 36720465.
  42. ^ Jiang, Qi-Qi; Tian, Xin-Yu; Bao, A-Gula; Bao, Yongsheng; Baiyin, Menghe (August 2021). "Assembly of new quaternary TM-Cu-Ge-Se compounds (TM = Ni, Mn) by the combination of two types of metal coordination geometries". Inorganic Chemistry Communications. 130: 108683. doi:10.1016/j.inoche.2021.108683. S2CID 236383545.
  43. Zhang, Yingying; Hu, Dandan; Yang, Huajun; Lin, Jian; Wu, Tao (July 2017). "Synthesis, crystal structure, near-IR photoelectric response of two 1-D selenides: [Cu 2 MSe 5 ]·[Mn(H + -en) 2 (en)] (M=Ge, Sn)". Journal of Solid State Chemistry. 251: 61–64. Bibcode:2017JSSCh.251...61Z. doi:10.1016/j.jssc.2017.04.006.
  44. ^ Li, Guang-mao; Liu, Qiong; Wu, Kui; Yang, Zhi-hua; Pan, Shi-lie (2017). "Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses". Dalton Transactions. 46 (9): 2778–2784. doi:10.1039/C7DT00087A. ISSN 1477-9226. PMID 28165518.
  45. Zhou, Molin; Li, Chao; Li, Xiaoshuang; Yao, Jiyong; Wu, Yicheng (2016). "K 2 Sn 2 ZnSe 6 , Na 2 Ge 2 ZnSe 6 , and Na 2 In 2 GeSe 6 : a new series of quaternary selenides with intriguing structural diversity and nonlinear optical properties". Dalton Transactions. 45 (18): 7627–7633. doi:10.1039/C6DT00143B. ISSN 1477-9226. PMID 27049006.
  46. ^ Sinagra, Charles W.; Saouma, Felix O.; Otieno, Calford O.; Lapidus, Saul H.; Zhang, Jian-Han; Craig, Andrew J.; Grima-Gallardo, Pedro; Brant, Jacilynn A.; Rosmus, Kimberly A.; Rosello, Kate E.; Jang, Joon I. (December 2021). "Synthesis, structure, linear and nonlinear optical properties of noncentrosymmetric quaternary diamond-like semiconductors, Cu2ZnGeSe4 (CZGSe) and the novel Cu4ZnGe2Se7". Journal of Alloys and Compounds. 888: 161499. doi:10.1016/j.jallcom.2021.161499. OSTI 1834616.
  47. Philippidis, Aggelos; Trikalitis, Pantelis N. (October 2009). "(H2NC4H8NCH2CH2NH2)(HNCH2CH2NH2)3Zn2Ge2Se8: A new, templated one-dimensional ternary semiconductor stabilized by mixed organic cations". Polyhedron. 28 (15): 3193–3198. doi:10.1016/j.poly.2009.04.028.
  48. ^ Wang, Jingrui; Li, Peng; Cai, Ting; Yang, Dan-Dan; Xiong, Wei-Wei (July 2018). "Four two-dimensional ternary selenides based on group 13 and 14 metals: Syntheses, crystal structures, and electrochemical properties". Journal of Solid State Chemistry. 263: 88–93. Bibcode:2018JSSCh.263...88W. doi:10.1016/j.jssc.2018.04.018. S2CID 103292702.
  49. ^ Li, Xiaoshuang; Li, Chao; Gong, Pifu; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2016). "Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 20". Dalton Transactions. 45 (2): 532–538. doi:10.1039/C5DT03682H. ISSN 1477-9226. PMID 26599138.
  50. ^ Friedrich, Daniel; Byun, Hye Ryung; Hao, Shiqiang; Patel, Shane; Wolverton, Chris; Jang, Joon Ik; Kanatzidis, Mercouri G. (2020-10-14). "Layered and Cubic Semiconductors A Ga M ′ Q 4 ( A + = K + , Rb + , Cs + , Tl + ; M ′ 4+ = Ge 4+ , Sn 4+ ; Q 2– = S 2– , Se 2– ) and High Third-Harmonic Generation". Journal of the American Chemical Society. 142 (41): 17730–17742. doi:10.1021/jacs.0c08638. ISSN 0002-7863. PMID 32933252. S2CID 221748402.
  51. ^ Li, Xiao-Hui; Suen, Nian-Tzu; Chi, Yang; Sun, Yueling; Gong, Anhua; Xue, Huaiguo; Guo, Sheng-Ping (2019-10-07). "Partial Congener Substitution Induced Centrosymmetric to Noncentrosymmetric Transformation Witnessed by K 3 Ga 3 (Ge 7– x M x )Se 20 (M = Si, Sn) and Their Nonlinear Optical Properties". Inorganic Chemistry. 58 (19): 13250–13257. doi:10.1021/acs.inorgchem.9b02113. ISSN 0020-1669. PMID 31553596. S2CID 203441685.
  52. ^ Klepp, Kurt O.; Fabian, Ferdinand (1999-12-01). "New Chalcogenogermanates with Adamantane Type Complex Anions: Preparation and Crystal Structures of K 4 Ge 4 S 10 ; Rb 4 Ge 4 S 10 , Rb 4 Ge 4 Se 10 , and Cs 4 Ge 4 Se 10". Zeitschrift für Naturforschung B. 54 (12): 1499–1504. doi:10.1515/znb-1999-1204. ISSN 1865-7117. S2CID 196894673.
  53. ^ Liu, Bin-Wen; Zhang, Min-Yi; Jiang, Xiao-Ming; Li, Shu-Fang; Zeng, Hui-Yi; Wang, Guo-Qiang; Fan, Yu-Hang; Su, Yong-Fei; Li, Chunsen; Guo, Guo-Cong; Huang, Jin-Shun (2017-11-14). "Large Second-Harmonic Generation Responses Achieved by the Dimeric [Ge 2 Se 4 (μ-Se 2 )] 4– Functional Motif in Polar Polyselenides A 4 Ge 4 Se 12 (A = Rb, Cs)". Chemistry of Materials. 29 (21): 9200–9207. doi:10.1021/acs.chemmater.7b03046. ISSN 0897-4756.
  54. ^ Hu, Xiao-Ning; Xiong, Lin; Wu, Li-Ming (2018-05-02). "Six New Members of the A 2 M II M IV 3 Q 8 Family and Their Structural Relationship". Crystal Growth & Design. 18 (5): 3124–3131. doi:10.1021/acs.cgd.8b00247. ISSN 1528-7483.
  55. ^ Loose, Anja; Sheldrick, William S. (1997-06-01). "Quaternary Selenidogermanates(IV) A 3 [AgGe 4 Se 10 ]·2H 2 O and A 2 [MnGe 4 Se 10 ]·3H 2 O (A = Rb, Cs) with Open Framework Structures". Zeitschrift für Naturforschung B. 52 (6): 687–692. doi:10.1515/znb-1997-0604. ISSN 1865-7117. S2CID 62785714.
  56. Rothenberger, Alexander; Shafaei-Fallah, Maryam; Kanatzidis, Mercouri G. (2010-11-01). "Aluminosilicate Relatives: Chalcogenoaluminogermanates Rb 3 (AlQ 2 ) 3 (GeQ 2 ) 7 (Q = S, Se)". Inorganic Chemistry. 49 (21): 9749–9751. doi:10.1021/ic101627v. ISSN 0020-1669. PMID 20932019.
  57. ^ Menezes, Luke T.; Assoud, Abdeljalil; Zhang, Weiguo; Halasyamani, P. Shiv; Kleinke, Holger (2020-10-19). "Effect of Pb Substitution in Sr 2-x Pb x GeSe 4 on Crystal Structures and Nonlinear Optical Properties Predicted by DFT Calculations". Inorganic Chemistry. 59 (20): 15028–15035. doi:10.1021/acs.inorgchem.0c01949. ISSN 0020-1669. PMID 32986411. S2CID 222151303.
  58. Pocha, R.; Tampier, M.; Hoffmann, R.-D.; Mosel, B. D.; Pöttgen, R.; Johrendt, Dirk (July 2003). "Crystal Structures and Properties of the Thiostannates Eu2SNS4 and Sr2SNS4 and the Selenogermanate γ-Sr2GeSe4". Zeitschrift für anorganische und allgemeine Chemie. 629 (78): 1379–1384. doi:10.1002/zaac.200300091.
  59. ^ Johrendt, Dirk; Tampier, Markus (2000-03-17). "Strontium Selenogermanate(III) and Barium Selenogermanate(II,IV): Synthesis, Crystal Structures, and Chemical Bonding". Chemistry - A European Journal. 6 (6): 994–998. doi:10.1002/(SICI)1521-3765(20000317)6:6<994::AID-CHEM994>3.0.CO;2-H. ISSN 0947-6539. PMID 10785819.
  60. ^ Tang, Shimei; Zhou, Jian; Zou, Hua-Hong; Liu, Xing; Zhang, Li (2018-02-05). "A Series of Lanthanide Selenidogermanates: The First Coexistence of Three Types of Selenidogermanate Units in the Same Architecture". Inorganic Chemistry. 57 (3): 1242–1250. doi:10.1021/acs.inorgchem.7b02659. ISSN 0020-1669. PMID 29319302.
  61. ^ Tang, Shimei; Cao, Shumei; Zhou, Jian (July 2018). "A Series of Lanthanide Chalcogenidogermanates Displaying Two Types of 1-D Polymeric Chains". Journal of Cluster Science. 29 (4): 777–783. doi:10.1007/s10876-018-1402-6. ISSN 1040-7278. S2CID 103263516.
  62. ^ Choudhury, Amitava; Strobel, Sabine; Martin, Benjamin R.; Karst, Angela L.; Dorhout, Peter K. (2007-03-01). "Synthesis of a Family of Solids through the Building-Block Approach: A Case Study with Ag + Substitution in the Ternary Na−Ge−Se System". Inorganic Chemistry. 46 (6): 2017–2027. doi:10.1021/ic061064z. ISSN 0020-1669. PMID 17302403.
  63. Yao, Hua–Gang; Zhang, Ren–Chun; Ji, Shou–Hua; Ji, Min; An, Yong–Lin; Ning, Gui–Ling (November 2010). "Mineralizer effect on the synthesis of two types of one-dimensional chains silver-selenogermanate and selenostannate". Inorganic Chemistry Communications. 13 (11): 1296–1298. doi:10.1016/j.inoche.2010.07.020.
  64. Al-Zahrani, H. Y. S.; Alsulami, Abdullah (April 2023). "Tailoring the structural, optical, and optoelectrical parameters of the thermally evaporated Ag2FeGeSe4 thin films". Journal of Materials Science: Materials in Electronics. 34 (10). doi:10.1007/s10854-023-10275-3. ISSN 0957-4522. S2CID 257902596.
  65. Dang, Junhui; Wang, Naizheng; Yao, Jiyong; Wu, Yuandong; Lin, Zheshuai; Mei, Dajiang (2022-07-12). "AgGaGeSe4: An Infrared Nonlinear Quaternary Selenide with Good Performance". Symmetry. 14 (7): 1426. Bibcode:2022Symm...14.1426D. doi:10.3390/sym14071426. ISSN 2073-8994.
  66. ^ Jiang, Qi-Qi; Ling, Ling; Baiyin, Menghe (March 2020). "New quaternary selenogermanates of Rb2Ag2GeSe4 and Cs2Cu2GeSe4". Inorganic Chemistry Communications. 113: 107794. doi:10.1016/j.inoche.2020.107794. S2CID 214186737.
  67. ^ Qiu, Zhi-Xin; Pei, Shao-Min; Chen, Wen-Fa; Jiang, Xiao-Ming; Liu, Bin-Wen; Guo, Guo-Cong (2022). "AAg 3 Ga 8 Se 14 (A = Rb, Cs): second-harmonic generation responses realized through the parallel arrangement of AgSe 4 and GaSe 4 tetrahedrons". Dalton Transactions. 51 (29): 11048–11053. doi:10.1039/D2DT01614A. ISSN 1477-9226. PMID 35796155. S2CID 250004504.
  68. McKeown Wessler, Garrett C.; Wang, Tianlin; Blum, Volker; Mitzi, David B. (2022-02-14). "Cubic Crystal Structure Formation and Optical Properties within the Ag–B II –M IV –X (B II = Sr, Pb; M IV = Si, Ge, Sn; X = S, Se) Family of Semiconductors". Inorganic Chemistry. 61 (6): 2929–2944. doi:10.1021/acs.inorgchem.1c03805. ISSN 0020-1669. OSTI 1865836. PMID 35107292. S2CID 246474677.
  69. Guo, Yangwu; Li, Xiaoshuang; Feng, Kai; Li, Chao; Zhou, Molin; Wu, Yicheng; Yao, Jiyong (2018-04-04). "Li 7 Cd 4.5 Ge 4 Se 16 and Li 6.4 Cd 4.8 Sn 4 Se 16 : Strong Nonlinear Optical Response in Quaternary Diamond-Like Selenide Networks". Chemistry: An Asian Journal. 13 (7): 871–876. doi:10.1002/asia.201800090. PMID 29392886.
  70. Ji, Bingheng; Wang, Fei; Wu, Kui; Zhang, Bingbing; Wang, Jian (2023-01-09). "d 6 versus d 10 , Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K 2 TGe 3 Ch 8 (T = Fe, Cd; Ch = S, Se)". Inorganic Chemistry. 62 (1): 574–582. doi:10.1021/acs.inorgchem.2c03852. ISSN 0020-1669. PMID 36574629.
  71. Dou, Yunwei; Chen, Ying; Li, Zhuang; Iyer, Abishek K.; Kang, Bin; Yin, Wenlong; Yao, Jiyong; Mar, Arthur (2019-02-06). "SrCdGeS 4 and SrCdGeSe 4 : Promising Infrared Nonlinear Optical Materials with Congruent-Melting Behavior". Crystal Growth & Design. 19 (2): 1206–1214. doi:10.1021/acs.cgd.8b01649. ISSN 1528-7483. S2CID 104442440.
  72. ^ Friedrich, Daniel; Hao, Shiqiang; Patel, Shane; Wolverton, Chris; Kanatzidis, Mercouri G. (2021-08-24). "Vast Structural and Polymorphic Varieties of Semiconductors AMM′Q 4 (A = K, Rb, Cs, Tl; M = Ga, In; M′ = Ge, Sn; Q = S, Se)". Chemistry of Materials. 33 (16): 6572–6583. doi:10.1021/acs.chemmater.1c02211. ISSN 0897-4756. S2CID 238682020.
  73. Wu, Xiaowen; Hu, Yi; Pan, Hui; Su, Zhi (2016). "Na 9 Sb(Ge 2 Q 6 ) 2 (Q = S, Se): two new antimony( iii ) quaternary chalcogenides with ethane-like [Ge 2 Q 6 ] 6− ligands". RSC Advances. 6 (101): 99475–99481. Bibcode:2016RSCAd...699475W. doi:10.1039/C6RA22000B. ISSN 2046-2069.
  74. Yu, Ching-Yi; Wang, Ming-Fang; Chung, Ming-Yang; Jang, Shyue-Ming; Huang, Jih-Chen; Lee, Chi-Shen (September 2008). "Synthesis and characterization of a new quaternary selenide Sr3GeSb2Se8". Solid State Sciences. 10 (9): 1145–1149. Bibcode:2008SSSci..10.1145Y. doi:10.1016/j.solidstatesciences.2007.12.010.
  75. ^ van Almsick, Tobias; Sheldrick, William S. (August 2005). "Methanolothermal Synthesis and Structures of the Quaternary Group 14 - Group 15 Cesium Selenidometalates Cs3AsGeSe5 and Cs4Ge2Se6". Zeitschrift für anorganische und allgemeine Chemie (in German). 631 (10): 1746–1748. doi:10.1002/zaac.200500136. ISSN 0044-2313.
  76. ^ Sheldrick, W. S.; Schaaf, B. (1994-05-01). "Darstellung und Kristallstruktur der Cäsium-Selenidogermanate(IV) Cs 4 Ge 4 Se 10 · 2CH 3 OH und Cs 4 Ge 2 Se 8 / Preparation and Crystal Structure of the Cesium Selenidogerm anates(IV) Cs 4 Ge 4 Se 10 · 2CH 3 OH and Cs 4 Ge 2 Se 8". Zeitschrift für Naturforschung B. 49 (5): 655–659. doi:10.1515/znb-1994-0515. ISSN 1865-7117. S2CID 97162430.
  77. ^ Morris, Collin D.; Li, Hao; Jin, Hosub; Malliakas, Christos D.; Peters, John A.; Trikalitis, Pantelis N.; Freeman, Arthur J.; Wessels, Bruce W.; Kanatzidis, Mercouri G. (2013-08-27). "Cs 2 M II M IV 3 Q 8 (Q = S, Se, Te): An Extensive Family of Layered Semiconductors with Diverse Band Gaps". Chemistry of Materials. 25 (16): 3344–3356. doi:10.1021/cm401817r. ISSN 0897-4756.
  78. Wang, Yingqi; Wang, Ruiqi; Liu, Qinglong; Lai, Xiaofang; Zhang, Xian; Chen, Haijie; Zheng, Chong; Lin, Jianhua; Huang, Fuqiang (2016). "Solvothermal synthesis, structure and physical properties of Cs[Cr(en) 2 MSe 4 ] (M = Ge, Sn) with [MSe 4 ] 4− tetrahedra as chelating ligand". Dalton Transactions. 45 (22): 9097–9102. doi:10.1039/C6DT00233A. ISSN 1477-9226. PMID 27164409.
  79. Ma, Ni; Xiong, Lin; Chen, Ling; Wu, Li-Ming (December 2019). "Vibration uncoupling of germanium with different valence states lowers thermal conductivity of Cs2Ge3Ga6Se14". Science China Materials. 62 (12): 1788–1797. doi:10.1007/s40843-019-1192-y. ISSN 2095-8226. S2CID 204962439.
  80. ^ Huang-Fu, Shang-Xiong; Shen, Jin-Ni; Lin, Hua; Chen, Ling; Wu, Li-Ming (2015-06-26). "Supercubooctahedron (Cs 6 Cl) 2 Cs 5 [Ga 15 Ge 9 Se 48 ] Exhibiting Both Cation and Anion Exchange". Chemistry: A European Journal. 21 (27): 9809–9815. doi:10.1002/chem.201405719. PMID 25982195.
  81. Wang, Ruiqi; Zhang, Xian; Huang, Fuqiang (October 2022). "[Cs6Cl][Ga5GeQ12] (Q = S, Se): two novel porous layered chalcohalides exhibiting two-band emission and ion exchange properties". Science China Chemistry. 65 (10): 1903–1910. doi:10.1007/s11426-022-1277-x. ISSN 1674-7291. S2CID 252363431.
  82. Wu, Yang-Yang; Xiong, Lin; Jia, Fei; Chen, Ling (2018-04-16). "Cs 2 Ge 3 In 6 Se 14 : A Structure Transformation Driven by the Size Preference and Its Properties". Inorganic Chemistry. 57 (8): 4667–4672. doi:10.1021/acs.inorgchem.8b00400. ISSN 0020-1669. PMID 29601192.
  83. ^ Melullis, Maike; Clérac, Rodolphe; Dehnen, Stefanie (2005). "Ternary Mn/Ge/Se anions from reactions of [Ba2(H2O)9][GeSe4]: Synthesis and characterization of compounds containing discrete or polymeric [Mn6Ge4Se17]6– units". Chemical Communications (48): 6008–6010. doi:10.1039/b513305j. ISSN 1359-7345. PMID 16333510.
  84. ^ Menezes, Luke T.; Richtik, Brooke N.; Assoud, Abdeljalil; Zeljkovic, Ivan D.; Farahi, Nader; Dolgos, Michelle; Kleinke, Holger (2023-01-09). "Ba 6 Ge 2 Se 12 and Ba 7 Ge 2 Se 17 : Two Centrosymmetric Barium Seleno-Germanates with Polyatomic Anion Disorder". Inorganic Chemistry. 62 (1): 285–294. doi:10.1021/acs.inorgchem.2c03373. ISSN 0020-1669. PMID 36572592. S2CID 255211186.
  85. Liu, Peng-Fei; Li, Yan-Yan; Zheng, Yu-Jun; Yu, Ju-Song; Duan, Rui-Huan; Chen, Hong; Lin, Hua; Chen, Ling; Wu, Li-Ming (2017). "Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 2". Dalton Transactions. 46 (8): 2715–2721. doi:10.1039/C6DT04294E. ISSN 1477-9226. PMID 28174766.
  86. Nian, Leyan; Huang, Junben; Wu, Kui; Su, Zhi; Yang, Zhihua; Pan, Shilie (2017). "BaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations". RSC Advances. 7 (47): 29378–29385. Bibcode:2017RSCAd...729378N. doi:10.1039/C7RA05022D. ISSN 2046-2069.
  87. Yin, Wenlong; Iyer, Abishek K.; Li, Chao; Yao, Jiyong; Mar, Arthur (June 2017). "Noncentrosymmetric chalcogenides BaZnSiSe4 and BaZnGeSe4 featuring one-dimensional structures". Journal of Alloys and Compounds. 708: 414–421. doi:10.1016/j.jallcom.2017.03.009.
  88. Abudurusuli, Ailijiang; Li, Junjie; Tong, Tinghao; Yang, Zhihua; Pan, Shilie (2020-04-20). "LiBa 4 Ga 5 Q 12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold". Inorganic Chemistry. 59 (8): 5674–5682. doi:10.1021/acs.inorgchem.0c00431. ISSN 0020-1669. PMID 32248682. S2CID 214811024.
  89. Yuan, Fang-Yu; Lin, Chen-Sheng; Huang, Yi-Zhi; Zhang, Hao; Zhou, An-Yi; Chai, Guo-Liang; Cheng, Wen-Dan (October 2021). "BaCdGeSe4: Synthesis, structure and nonlinear optical properties". Journal of Solid State Chemistry. 302: 122352. Bibcode:2021JSSCh.30222352Y. doi:10.1016/j.jssc.2021.122352.
  90. Yuan, Fang-Yu; Huang, Yi-Zhi; Zhang, Hao; Lin, Chen-Sheng; Chai, Guo-liang; Cheng, Wen-Dan (2021-10-18). "Ba 4 GeSb 2 Se 11 : An Infrared Nonlinear Optical Crystal with a V-Shaped Se 3 2– Group Possessing a Large Contribution to the SHG Response". Inorganic Chemistry. 60 (20): 15593–15598. doi:10.1021/acs.inorgchem.1c02197. ISSN 0020-1669. PMID 34590833. S2CID 238230414.
  91. ^ Cicirello, Gary; Wu, Kui; Zhang, Bing Bing; Wang, Jian (2021). "Applying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)". Inorganic Chemistry Frontiers. 8 (22): 4914–4923. doi:10.1039/D1QI00879J. ISSN 2052-1553. S2CID 239429516.
  92. Martin, B. R.; Knaust, J. M.; Dorhout, P. K. (April 2005). "Crystal structure of nonasodium lanthanum(III) bis[hexaselenodigermanate], Na9La[Ge2Se6]2". Zeitschrift für Kristallographie - New Crystal Structures. 220 (1–4): 314. doi:10.1524/ncrs.2005.220.14.314. ISSN 2197-4578. S2CID 201120800.
  93. Assoud, Abdeljalil; Soheilnia, Navid; Kleinke, Holger (July 2004). "Crystal and electronic structure of the red semiconductor Ba4LaSbGe3Se13 comprising the complex anion [Ge2Se7–Sb2Se4–Ge2Se7]14−". Journal of Solid State Chemistry. 177 (7): 2249–2254. Bibcode:2004JSSCh.177.2249A. doi:10.1016/j.jssc.2004.03.008.
  94. Choudhury, Amitava; Polyakova, Larisa A.; Hartenbach, Ingo; Schleid, Thomas; Dorhout, Peter K. (November 2006). "Synthesis, Structures, and Properties of Layered Quaternary Chalcogenides of the General Formula ALnEQ4 (A = K, Rb; Ln = Ce, Pr, Eu; E = Si, Ge; Q = S, Se)". Zeitschrift für anorganische und allgemeine Chemie (in German). 632 (15): 2395–2401. doi:10.1002/zaac.200600226.
  95. ^ Tang, Shimei; Liu, Xing; Zhou, Jian (September 2017). "A Series of Dimeric Selenidogermanates with Lanthanide Complexes of Multidentate Chelating Amines". Journal of Cluster Science. 28 (5): 2589–2600. doi:10.1007/s10876-017-1223-z. ISSN 1040-7278. S2CID 98926481.
  96. Martin, Benjamin R.; Polyakova, Larisa A.; Dorhout, Peter K. (February 2006). "Synthesis and characterization of a family of two related quaternary selenides: Na8Eu2(Si2Se6)2 and Na9Sm(Ge2Se6)2". Journal of Alloys and Compounds. 408–412: 490–495. doi:10.1016/j.jallcom.2004.12.091.
  97. ^ Iyer, Ratnasabapathy G; Aitken, Jennifer A; Kanatzidis, Mercouri G (May 2004). "Noncentrosymmetric cubic thio- and selenogermanates: A0.5M1.75GeQ4 (A=Ag, Cu, Na; M=Pb, Eu; Q=S, Se)". Solid State Sciences. 6 (5): 451–459. Bibcode:2004SSSci...6..451I. doi:10.1016/j.solidstatesciences.2004.03.001.
  98. Choudhury, Amitava; Dorhout, Peter K. (2006-07-01). "Destruction of Noncentrosymmetry through Chalcogenide Salt Inclusion". Inorganic Chemistry. 45 (14): 5245–5247. doi:10.1021/ic060294a. ISSN 0020-1669. PMID 16813377.
  99. ^ Martin, Benjamin R.; Dorhout, Peter K. (2004-01-01). "Molten Flux Synthesis of an Analogous Series of Layered Alkali Samarium Selenogermanate Compounds". Inorganic Chemistry. 43 (1): 385–391. doi:10.1021/ic034724y. ISSN 0020-1669. PMID 14704091.
  100. ^ Tampier, M.; Johrendt, D.; Pöttgen, R.; Kotzyba, G.; Rosenhahn, C.; Mosel, B. D. (2002-02-01). "Crystal Structures and Properties of Eu 2 GeSe 4 and Eu 2 Ge 2 Se 5". Zeitschrift für Naturforschung B. 57 (2): 133–140. doi:10.1515/znb-2002-0201. ISSN 1865-7117. S2CID 197320389.
  101. ^ Tang, Weiwei; Liang, Jingjing; Jiang, Wenqing; Wu, Bing; Zhang, Yong; Jia, Dingxian (September 2011). "The First Examples of Selenidogermanate Salts with Lanthanide Complex Counter Cations: Solvothermal Syntheses and Characterizations of [{Ln(en)3}2(μ-OH)2]Ge2Se6 (Ln = Eu, Ho) and [{Ho(dien)2}2(μ-OH)2]Ge2Se6". Zeitschrift für anorganische und allgemeine Chemie. 637 (11): 1539–1544. doi:10.1002/zaac.201100167.
  102. ^ Chen, Ruihong; Tang, Weiwei; Liang, Jingjing; Jiang, Wenqing; Zhang, Yong; Jia, Dingxian (2012). "The first μ-Ge2Se8 ligand to lanthanide(iii) centers: solvothermal syntheses and characterizations of lanthanide selenidogermanate complexes with a pentadentate polyamine as a co-ligand". Dalton Transactions. 41 (40): 12439–12445. doi:10.1039/c2dt30960b. ISSN 1477-9226. PMID 22949067.
  103. ^ Choudhury, Amitava; Polyakova, Larisa A.; Strobel, Sabine; Dorhout, Peter K. (April 2007). "Two non-centrosymmetric cubic seleno-germanates related to CsCl-type structure: Synthesis, structure, magnetic and optical properties". Journal of Solid State Chemistry. 180 (4): 1381–1389. Bibcode:2007JSSCh.180.1381C. doi:10.1016/j.jssc.2007.02.002.
  104. Evenson; Dorhout, Peter K. (2001-05-01). "Synthesis and Characterization of Four New Europium Group XIV Chalcogenides: K 2 EuTSe 5 and KEuTS 4 (T = Si, Ge)". Inorganic Chemistry. 40 (10): 2409–2414. doi:10.1021/ic001248s. ISSN 0020-1669. PMID 11327920.
  105. Xing, Wenhao; Wang, Naizheng; Guo, Yangwu; Li, Zhuang; Tang, Jian; Kang, Kaijin; Yin, Wenlong; Lin, Zheshuai; Yao, Jiyong; Kang, Bin (2019). "Two rare-earth-based quaternary chalcogenides EuCdGeQ 4 (Q = S, Se) with strong second-harmonic generation". Dalton Transactions. 48 (47): 17620–17625. doi:10.1039/C9DT03755A. ISSN 1477-9226. PMID 31755500. S2CID 208229363.
  106. ^ Tang, Shimei; Zhou, Jian; Zou, Hua-Hong; Liu, Xing (2018-04-18). "Two new 1-D lanthanide selenidogermanates with the [Ge 2 Se 6 ] 4− anion as a bridging ligand to a lanthanide complex cation". Journal of Coordination Chemistry. 71 (8): 1093–1101. doi:10.1080/00958972.2018.1449209. ISSN 0095-8972. S2CID 103352365.
  107. ^ Gao, Lihua; Xu, Jingjing; Tian, Xinyu; Zhang, Bingbing; Wu, Xiaowen; Wu, Kui (2022-06-26). "AgGaSe 2 -Inspired Nonlinear Optical Materials: Tetrel Selenides of Alkali Metals and Mercury". Chemistry of Materials. 34 (13): 5991–5998. doi:10.1021/acs.chemmater.2c01011. ISSN 0897-4756. S2CID 250080020.
  108. ^ Guo, Yangwu; Liang, Fei; Yin, Wenlong; Li, Zhuang; Luo, Xiaoyu; Lin, Zhe-Shuai; Yao, Jiyong; Mar, Arthur; Wu, Yicheng (2019-04-23). "BaHgGeSe 4 and SrHgGeSe 4 : Two New Hg-Based Infrared Nonlinear Optical Materials". Chemistry of Materials. 31 (8): 3034–3040. doi:10.1021/acs.chemmater.9b01023. ISSN 0897-4756. S2CID 131951753.
  109. Xing, Wenhao; Tang, Chunlan; Wang, Naizheng; Li, Chunxiao; Li, Zhuang; Wu, Jieyun; Lin, Zheshuai; Yao, Jiyong; Yin, Wenlong; Kang, Bin (2020-12-21). "EuHgGeSe 4 and EuHgSnS 4 : Two Quaternary Eu-Based Infrared Nonlinear Optical Materials with Strong Second-Harmonic-Generation Responses". Inorganic Chemistry. 59 (24): 18452–18460. doi:10.1021/acs.inorgchem.0c03176. ISSN 0020-1669. PMID 33256399. S2CID 227245551.
  110. Babizhetskyy, Volodymyr; Levytskyy, Volodymyr; Smetana, Volodymyr; Wilk-Kozubek, Magdalena; Tsisar, Oksana; Piskach, Lyudmyla; Parasyuk, Oleg; Mudring, Anja-Verena (2020-02-25). "New cation-disordered quaternary selenides Tl 2 Ga 2 Tt Se 6 ( Tt =Ge, Sn)". Zeitschrift für Naturforschung B. 75 (1–2): 135–142. doi:10.1515/znb-2019-0169. ISSN 1865-7117. S2CID 211229264.
  111. Khyzhun, O.Y.; Parasyuk, O.V.; Tsisar, O.V.; Piskach, L.V.; Myronchuk, G.L.; Levytskyy, V.O.; Babizhetskyy, V.S. (October 2017). "New quaternary thallium indium germanium selenide TlInGe 2 Se 6 : Crystal and electronic structure". Journal of Solid State Chemistry. 254: 103–108. Bibcode:2017JSSCh.254..103K. doi:10.1016/j.jssc.2017.07.014.
  112. ^ Bellagra, H. K.; Kogut, Y. M.; Piskach, L. V. (February 2023). "Component Interaction in the Quasi-Ternary System PbSe–Ga2Se3–GeSe2". Journal of Phase Equilibria and Diffusion. 44 (1): 3–16. doi:10.1007/s11669-022-01017-9. ISSN 1547-7037. S2CID 254430712.
  113. Assoud, Abdeljalil; Kleinke, Holger (2017-12-15). "A Polyselenide with a Novel Se 7 8– Unit: the Structure of Sr 19– x Pb x Ge 11 Se 44 with x = 5.0 and 6.4". European Journal of Inorganic Chemistry. 2017 (46): 5515–5520. doi:10.1002/ejic.201701180. ISSN 1434-1948.
  114. Reshak, A. H.; Kogut, Y. M.; Fedorchuk, A. O.; Zamuruyeva, O. V.; Myronchuk, G. L.; Parasyuk, O. V.; Kamarudin, H.; Auluck, S.; Plucinski, K. J.; Bila, Jiri (2013). "Electronic and optical features of the mixed crystals Ag0.5Pb1.75Ge(S1–xSex)4". Journal of Materials Chemistry C. 1 (31): 4667. doi:10.1039/c3tc30713a. ISSN 2050-7526.
Salts and covalent derivatives of the selenide ion
H2Se
H2Se2
+H
-H 		He
Li2Se Be SexByOz CSe2
OCSe
(CH3)2Se 		(NH4)2Se O F Ne
Na2Se MgSe Al2Se3 Si PxSey
-P 		+S Cl Ar
K2Se CaSe Sc2Se3 TiSe2 V CrSe
Cr2Se3 		MnSe
MnSe2 		FeSe CoSe NiSe Cu2Se
CuSe 		ZnSe GaSe
Ga2Se3
-Ga 		GeSe
GeSe2
-Ge 		As2Se3
As4Se3 		Se
n 		Br Kr
Rb2Se SrSe Y2Se3 Zr NbSe2
NbSe3 		MoSe2 Tc Ru Rh Pd Ag2Se CdSe InSe
In2Se3 		SnSe
SnSe2
-Sn 		Sb2Se3 Te +I Xe
Cs2Se BaSe * LuSe
Lu2Se3 		Hf TaSe2 WSe2
WSe3 		ReSe2 Os Ir PtSe2 Au HgSe Tl2Se PbSe Bi2Se3 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg CnSe Nh Fl Mc Lv Ts Og
 
* LaSe
La2Se3 		CeSe
Ce2Se3 		PrSe
Pr2Se3 		NdSe
Nd2Se3 		Pm SmSe
Sm2Se3 		EuSe
Eu2Se3 		GdSe
Gd2Se3 		TbSe
Tb2Se3 		DySe
Dy2Se3 		HoSe
Ho2Se3 		ErSe
Er2Se3 		TmSe
Tm2Se3 		YbSe
Yb2Se3
** Ac ThSe2 Pa USe2 Np PuSe Am Cm Bk Cf Es Fm Md No
Germanium compounds
Ge(II)
Ge(IV)
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