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Iodate sulfate

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Iodate sulfates are mixed anion compounds that contain both iodate and sulfate anions. Iodate sulfates have been investigated as optical second harmonic generators, and for separation of rare earth elements. Related compounds include the iodate selenates and chromate iodates.


Iodate sulfates can be produced from water solutions of iodic acid and sulfate salts.

List

formula name formula

weight

system space group cell Å volume density comments ref
Na7(IO3)(SO4)3 624.01 orthorhombic P212121 a=6.839 b=10.851 c=18.519 Z=4 1374.2 3.016 at 100K; band gap 4.83; SHQ 0.5×KDP; birefringence 0.075 at 1064 nm
Na9(IO3)(SO4)4 Hectorfloresite monoclinic P21/a a = 18.775 b = 6.9356 c = 14.239 β = 108.91° Z = 4
K2SO4·HIO3 350.17 monoclinic P21/n a=7.4215 b=7.1578 c=13.802 β=93.330° Z=4 731.9 3.178 colourless; birefingence 0.14 at 589.3 nm; UV edge 275 nm
K3Na5Mg5(IO3)6(SO4)6(H2O)5 trigonal P3c1
K7.2Na8.8Mg10(IO3)12(SO4)12(H2O)12 Fuenzalidaite trigonal P3c1 a = 9.4643 c = 27.336 2,120.52 colourless; Uniaxial (-) nω = 1.622 nε = 1.615; Birefringence = 0.007
Nb2O3(IO3)2(SO4) 679.68 monoclinic P21 a=5.299 b=20.479 c=5.452 β=119.095° Z=2 517.0 4.366 band gap 3.25; SHG 6 × KDP; birefringence 0.22 at 1064 nm; stable below 580 °C
Ce(IO3)2(SO4) CISO 585.98 orthorhombic P212121 a=7.5366 b=8.9787 c=11.6121 Z=4 785.78 4.953 yellow; SHG 3.5 × KDP; birefringence 0.259 at 546 nm
Sm(IO3)(SO4) monoclinic P21/c a=9.3148 b=6.8678 c=8.2852 β=104.701°
Sm2(IO3)3(SO4)OH·3H2O triclinic P1 a 7.3858 b 9.6166 c 11.8629 α=66.482° β=76.884° γ=69.101°
Eu(IO3)(SO4) monoclinic P21/c a=9.3083 b=6.8460 c=8.2575 β=104.696°
Eu2(IO3)3(SO4)OH·3H2O triclinic P1 a=7.3666 b=9.5817 c=11.8263 α=66.5365° β=76.8591° γ=69.1131°
Dy(IO3)(SO4)(H2O) orthorhombic P212121 a=7.3088 b=9.4824 c=11.7302 α=66.6573° β=76.8745° γ=69.2970°
Dy(IO3)(SO4)(H2O)3 orthorhombic P212121 a=6.682 b=8.791 c=13.632
Dy2(IO3)3(SO4)OH·3H2O triclinic P1
Hg2(IO3)2(SO4) monoclinic C2/c a=12.040 b=4.7133 c=15.533 β=102.43°
Hg2(IO3)2(SO4)(H2O) monoclinic C2 a=11.767 b=4.9190 c=7.8076 β=97.10° band gap 3.98 eV; SHG 6 × KDP; dehydrate 250 °C
Bi(IO3)(SO4) 479.94 monoclinic P21/c a=9.4355 b=6.9168 c=8.3374 β=105.168° Z=4 525.17 6.070 band gap 3.91 eV; birefringence 0.087 at 1064 nm; colourless
Bi2O(SO4)(IO3)2 monoclinic P21/n a=7.2391 b=17.907 c=7.7964 β = 109.652° Z =4
AgBi(SO4)(IO3)2 1525.42 triclinic P1 a=5.5189 b=6.9129 c=11.8527 α=90.598° β=92.151° γ=109.895° Z=1 424.78 5.963 colourless; SHG 3.0 × KDP
CdBi(IO3)(SO4)2 688.40 monoclinic P21/c a=12.777 b=6.8491 c=9.984 β=103.23° Z=4 850.5 5.376 band gap 4.03 eV; birefringence 0.100 at 1064 nm

References

  1. ^ Lu, Huangjie; Guo, Xiaojing; Wang, Yaxing; Diefenbach, Kariem; Chen, Lanhua; Wang, Jian-Qiang; Lin, Jian; Wang, Shuao (2019). "Size-dependent selective crystallization using an inorganic mixed-oxoanion system for lanthanide separation". Dalton Transactions. 48 (34): 12808–12811. doi:10.1039/C9DT02387A. ISSN 1477-9226. PMID 31348473. S2CID 198911627.
  2. Chen, Qian-Qian; Hu, Chun-Li; Li, Bing-Xuan; Mao, Jiang-Gao (2023). "[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology". Inorganic Chemistry Frontiers. 10 (10): 3121–3130. doi:10.1039/D3QI00415E. ISSN 2052-1553. S2CID 258123310.
  3. Sullens, Tyler A.; Almond, Philip M.; Byrd, Jessica A.; Beitz, James V.; Bray, Travis H.; Albrecht-Schmitt, Thomas E. (April 2006). "Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)2". Journal of Solid State Chemistry. 179 (4): 1192–1201. Bibcode:2006JSSCh.179.1192S. doi:10.1016/j.jssc.2006.01.017.
  4. ^ Shi, Long; Mei, Dajiang; Xu, Jingli; Wu, Yuandong (January 2017). "Bi 2 O(XO 4 )(IO 3 ) 2 (X = S, Se, Cr): Three-dimensional frameworks containing [Bi 4 O 2 ] 8+ clusters". Solid State Sciences. 63: 54–61. Bibcode:2017SSSci..63...54S. doi:10.1016/j.solidstatesciences.2016.11.010.
  5. ^ Ding, Mengmeng; Yu, Hongwei; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng (2021). "Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units". Chemical Communications. 57 (75): 9598–9601. doi:10.1039/D1CC03483A. ISSN 1359-7345. PMID 34546233. S2CID 237584872.
  6. George E. Ericksen; Howard T. Evans; Mary E. Mrose; James J. Mcgee; John W. Marinenko; Judith A. Konnert (1 October 1989). "Mineralogical studies of the nitrate deposits of Chile; VI, Hectorfloresite, Na9(IO3(SO4)4, a new saline mineral". American Mineralogist. 74 (9–10): 1207–1214. Retrieved 2023-09-11.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  7. Bai, Zhiyong; Ok, Kang Min (2023). "Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3". Inorganic Chemistry Frontiers. 10 (6): 1919–1925. doi:10.1039/D3QI00192J. ISSN 2052-1553. S2CID 257071174.
  8. "Fuenzalidaite". Mindat.org.
  9. Konnert, Judith A.; Evans, Howard T.; McGee, James J.; Ericksen, George E. (October 1994). "Mineralogical studies of the nitrate deposits of Chile: VII. Two new saline minerals with the composition K6(Na,K)4Na6Mg10(XO4)12(IO3)12·12H2O: Fuenzalidaite (X = S) and carlosruizite (X = Se)". American Mineralogist. 79 (9–10): 1003–1008. Bibcode:1994AmMin..79.1003K. Retrieved 2023-09-11.
  10. Tang, Hong-Xin; Zhang, Yu-Xiao; Zhuo, Chao; Fu, Rui-Biao; Lin, Hua; Ma, Zu-Ju; Wu, Xin-Tao (2019-03-18). "A Niobium Oxyiodate Sulfate with a Strong Second-Harmonic-Generation Response Built by Rational Multi-Component Design". Angewandte Chemie. 131 (12): 3864–3868. Bibcode:2019AngCh.131.3864T. doi:10.1002/ange.201813122. ISSN 0044-8249. S2CID 243005250.
  11. Wu, Tianhui; Jiang, Xingxing; Zhang, Yiran; Wang, Zujian; Sha, Hongyuan; Wu, Chao; Lin, Zheshuai; Huang, Zhipeng; Long, Xifa; Humphrey, Mark G.; Zhang, Chi (2021-12-14). "From CeF 2 (SO 4 )·H 2 O to Ce(IO 3 ) 2 (SO 4 ): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence". Chemistry of Materials. 33 (23): 9317–9325. doi:10.1021/acs.chemmater.1c03053. ISSN 0897-4756. S2CID 244494818.
  12. ^ Aslani, Ceren Kutahyali; Klepov, Vladislav V.; zur Loye, Hans-Conrad (July 2022). "Hydrothermal synthesis of new mixed-oxoanion materials: Rare earth iodate sulfates Sm(IO3)(SO4) and Ln2(IO3)3(SO4)OH·3H2O (Ln = Sm, Eu, Dy)". Solid State Sciences. 129: 106918. Bibcode:2022SSSci.12906918A. doi:10.1016/j.solidstatesciences.2022.106918.
  13. ^ Li, Yi-Lin; Ji, Meng-Ya; Hu, Chun-Li; Chen, Jin; Li, Bing-Xuan; Lin, Yuan; Mao, Jiang-Gao (April 2022). "Explorations of New SHG Materials in Mercury Iodate Sulfate System**". Chemistry – A European Journal. 28 (19): e202200001. doi:10.1002/chem.202200001. ISSN 0947-6539. PMID 35156759. S2CID 246813632.
  14. ^ Li, Yilin; Hu, Chunli; Chen, Jin; Mao, Jianggao (2021). "Two bismuth iodate sulfates with enhanced optical anisotropy". Dalton Transactions. 50 (44): 16139–16146. doi:10.1039/D1DT02514G. ISSN 1477-9226. PMID 34677566. S2CID 239456548.
  15. Liu, Hongming; Wu, Qingchen; Liu, Lili; Lin, Zheshuai; Halasyamani, P. Shiv; Chen, Xingguo; Qin, Jingui (2021). "AgBi(SO 4 )(IO 3 ) 2 : aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancement". Chemical Communications. 57 (30): 3712–3715. doi:10.1039/D0CC07862J. ISSN 1359-7345. PMID 33729224. S2CID 232262974.
Iodates
HIO3 He
LiIO3 Be +BO3 C (NH4)IO3
+NO3
O +F
-F
Ne
NaIO3 Mg(IO3)2 Al(IO3)3 Si P +SO4 Cl Ar
KIO3 Ca(IO3)2 Sc(IO3)3 Ti(IO3)4 V Cr Mn(IO3)2 Fe(IO3)2
Fe(IO3)3
Co(IO3)2 Ni(IO3)2 Cu(IO3)2 Zn(IO3)2 Ga(IO3)3 Ge As Se Br Kr
RbIO3 Sr(IO3)2 Y(IO3)3 Zr(IO3)4 Nb Mo Tc Ru Rh Pd AgIO3 Cd(IO3)2 In(IO3)3 Sn(IO3)4 Sb Te I Xe
CsIO3 Ba(IO3)2 * Lu(IO3)3 Hf(IO3)4 Ta W Re Os Ir Pt Au(IO3)3 Hg2(IO3)2
Hg(IO3)2
TlIO3 Pb(IO3)2 Bi(IO3)3 Po At Rn
Fr Ra(IO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(IO3)3 Ce(IO3)3 Pr(IO3)3 Nd(IO3)3 Pm(IO3)3 Sm(IO3)3 Eu(IO3)3 Gd(IO3)3 Tb(IO3)3 Dy(IO3)3 Ho(IO3)3 Er(IO3)3 Tm(IO3)3 Yb(IO3)3
** Ac Th(IO3)4 Pa U(IO3)2 Np(IO3)4 Pu(IO3)4 Am Cm Bk Cf Es Fm Md No
Compounds containing the sulfate group (SO2−4)
H2SO4 He
Li2SO4 BeSO4 B2S2O9
-BO3
+BO3
esters
ROSO−3
(RO)2SO2
+CO3
+C2O4
(NH4)2SO4
[N2H5]HSO4
(NH3OH)2SO4
NOHSO4
+NO3
H2OSO4 +F Ne
Na2SO4
NaHSO4
MgSO4 Al2(SO4)3
Al2SO4(OAc)4
Si +PO4 SO2−4
HSO3HSO4
(HSO4)2
+SO3
+Cl Ar
K2SO4
KHSO4
CaSO4 Sc2(SO4)3 TiOSO4 VSO4
V2(SO4)3
VOSO4
CrSO4
Cr2(SO4)3
MnSO4 FeSO4
Fe2(SO4)3
CoSO4
Co2(SO4)3
NiSO4
Ni2(SO4)3
CuSO4
Cu2SO4
SO4
ZnSO4 Ga2(SO4)3 Ge(SO4)2 As +SeO3 +Br Kr
RbHSO4
Rb2SO4
SrSO4 Y2(SO4)3 Zr(SO4)2 Nb2O2(SO4)3 MoO(SO4)2
MoO2(SO4)
Tc Ru(SO4)2 Rh2(SO4)3 PdSO4 Ag2SO4
AgSO4
CdSO4 In2(SO4)3 SnSO4
Sn(SO4)2
Sb2(SO4)3 TeOSO4 I2(SO4)3
(IO)2SO4
+IO3
Xe
Cs2SO4
CsHSO4
BaSO4 * Lu2(SO4)3 Hf(SO4)2 Ta WO(SO4)2 Re2O5(SO4)2 OsSO4
Os2(SO4)3
Os(SO4)2
IrSO4
Ir2(SO4)3
Pt2(SO4)5 AuSO4
Au2(SO4)3
Hg2SO4
HgSO4
Tl2SO4
Tl2(SO4)3
PbSO4
Pb(SO4)2
Bi2(SO4)3 PoSO4
Po(SO4)2
At Rn
Fr RaSO4 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La2(SO4)3 Ce2(SO4)3
Ce(SO4)2
Pr2(SO4)3 Nd2(SO4)3 Pm2(SO4)3 Sm2(SO4)3 EuSO4
Eu2(SO4)3
Gd2(SO4)3 Tb2(SO4)3 Dy2(SO4)3 Ho2(SO4)3 Er2(SO4)3 Tm2(SO4)3 Yb2(SO4)3
** Ac2(SO4)3 Th(SO4)2 Pa U2(SO4)3
U(SO4)2
UO2SO4
Np(SO4)2 Pu(SO4)2 Am2(SO4)3 Cm2(SO4)3 Bk Cf2(SO4)3 Es Fm Md No
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