Misplaced Pages

Yttrocene

Article snapshot taken from[REDACTED] with creative commons attribution-sharealike license. Give it a read and then ask your questions in the chat. We can research this topic together.
Yttrocene
Identifiers
CAS Number
3D model (JSmol)
InChI
  • InChI=1S/3C5H5.Y/c3*1-2-4-5-3-1;/h3*1-5H;/q3*-1;+3Key: OLQIFTSPAVIXCQ-UHFFFAOYSA-N
SMILES
  • c1ccc1.c2ccc2.c3ccc3.
Properties
Chemical formula C15H15Y
Molar mass 284.191 g·mol
Melting point 295 °C (568 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Yttrocene is an organoyttrium compound with the chemical formula Y(C5H5)3. It forms light yellow crystals and can be obtained by reacting anhydrous yttrium(III) chloride and sodium cyclopentadienide in tetrahydrofuran. It decomposes when exposed to water to produce cyclopentadiene and yttrium(III) hydroxide. Its thermal stability is between ferrocene and other 3D transition metal tricene complexes.

References

  1. ^ G. Wilkinson, J. M. Birmingham (Dec 1954). "CYCLOPENTADIENYL COMPOUNDS OF Sc, Y, La, Ce AND SOME LANTHANIDE ELEMENTS". Journal of the American Chemical Society. 76 (23): 6210. doi:10.1021/ja01652a114. ISSN 0002-7863. Archived from the original on 2021-07-16. Retrieved 2020-12-09.
  2. "Synthesis and fluorescence of triazoloazines derivatives". Voprosy Khimii i Khimicheskoi Tekhnologii (5): 71–76. Oct 2019. doi:10.32434/0321-4095-2019-126-5-71-76. ISSN 0321-4095.
Yttrium compounds
Yttrium(II)
Yttrium(III)
Organoyttrium(III) compounds
  • Y(C5H5)3
  • Y2(C2O4)3
    • Salts and covalent derivatives of the cyclopentadienide ion
    CpH He
    LiCp Be B CpMe N C5H4O F Ne
    NaCp MgCp2

    MgCpBr

    		Al Si P S Cl Ar
    K CaCp2 ScCp3 TiCp2Cl2

    (TiCp2Cl)2
    TiCpCl3
    TiCp2S5
    TiCp2(CO)2
    TiCp2Me2

    		VCp2

    VCpCh
    VCp2Cl2
    VCp(CO)4

    		CrCp2

    (CrCp(CO)3)2

    		MnCp2 FeCp2

    Fe(η-C5H4Li)2
    ((C5H5)Fe(C5H4))2
    (C5H4-C5H4)2Fe2
    FeCp2PF6
    FeCp(CO)2I

    		CoCp2

    CoCp(CO)2

    		NiCp2

    NiCpNO

    		Cu Zn Ga Ge As Se Br Kr
    Rb Sr Y(C5H5)3 ZrCp2Cl2

    ZrCp2ClH

    		NbCp2Cl2 MoCp2H2

    MoCp2Cl2
    (MoCp(CO)3)2

    		Tc RuCp2

    RuCp(PPh3)2Cl
    RuCp(MeCN)3PF6

    		RhCp2 PdCp(C3H5) Ag Cd InCp SnCp2 Sb Te I Xe
    Cs Ba * LuCp3 HfCp2Cl2 Ta (WCp(CO)3)2 ReCp2H OsCp2 IrCp2 Pt Au Hg TlCp PbCp2 Bi Po At Rn
    Fr Ra ** Lr Rf Db Sg Bh HsCp2 Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * LaCp3 CeCp3 PrCp3 NdCp3 PmCp3 SmCp3 Eu Gd Tb DyCp3 Ho ErCp3 TmCp3 YbCp3
    ** Ac ThCp3
    ThCp4         		Pa UCp4 Np Pu Am Cm Bk Cf Es Fm Md No
    Categories:
    Yttrocene Add topic