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Xenon nitrate

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Chemical compound
Xenon nitrate
Identifiers
3D model (JSmol)
InChI
  • InChI=1S/N2O6Xe/c3-1(4)7-9-8-2(5)6Key: DDUBBJJTDIIEIU-UHFFFAOYSA-N
SMILES
  • (=O)OO(=O)
Properties
Chemical formula N2O6Xe
Molar mass 255.301 g·mol
Related compounds
Related compounds FXeNO3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Xenon nitrate, also called xenon dinitrate, is an inorganic compound consisting of one xenon atom bonded to two nitrate groups. It can be made by reacting xenon difluoride with anhydrous nitric acid, but it only exists transiently before decomposing, and therefore it has not been isolated and fully characterized. A related compound, xenon fluoride nitrate, has been made and is stable enough to be studied in more detail.

Production

Attempted production has used the following reaction:

XeF2 + 2 HNO3 → Xe(NO3)2 + 2 HF

This reaction makes a red-brown solid. However, it decomposes spontaneously at 23 °C, turning blue temporarily while doing so:

Xe(NO3)2 → Xe + O2NOONO2 (an unstable nitrogen peroxide)

References

  1. Moran, Matthew D. (2007). Synthesis and Structural Characterization of new Xenon(II) Compounds and the Use of a Xenon(II) Cation as an Oxidant for the Preparation of Halogenated Hydrocarbons (PDF) (PhD). McMaster University. pp. 42, 99–145. Retrieved 4 Oct 2014.
  2. ^ Eisenberg, Max; Darryl D. DesMarteau (1970). "The reaction of xenon difluoride with some strong oxy-acids". Inorganic and Nuclear Chemistry Letters. 6 (1): 29–34. doi:10.1016/0020-1650(70)80279-3. ISSN 0020-1650.
Xenon compounds
Xenon(0)
Xenon(I)
Xenon(II)
Organoxenon(II) compounds
  • XeC6F5F
  • XeC6F5C2F3
  • XeC6F5CF3
  • Xe(C6F5)2
  • XeC6F5C6H2F3
  • XeC6F5CN
  • Xe(CF3)2
    • Xenon(IV)
    Organoxenon(IV) compounds
  • XeF2C6F5BF4
    • Xenon(VI)
    Xenon(VIII)
    Category:Xenon compounds
    Salts and covalent derivatives of the nitrate ion
    HNO3 He
    LiNO3 Be(NO3)2 B(NO3)−4 RONO2
    +CO3
    +C2O4     		NO3
    NH4NO3     		HOONO2 FNO3
    +F     		Ne
    NaNO3 Mg(NO3)2 Al(NO3)3
    Al(NO3)−4     		Si P +SO4 ClONO2
    +Cl     		Ar
    KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)2
    Fe(NO3)3     		Co(NO3)2
    Co(NO3)3     		Ni(NO3)2 CuNO3
    Cu(NO3)2     		Zn(NO3)2 Ga(NO3)3 Ge As +SeO3 BrNO3
    +Br     		Kr
    RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 NbO(NO3)3 MoO2(NO3)2 Tc Ru Rh(NO3)3 Pd(NO3)2 AgNO3 Cd(NO3)2 In(NO3)3 Sn(NO3)4 Sb4O4(OH)2(NO3)2 Te INO3
    +IO3     		Xe(NO3)2
    CsNO3 Ba(NO3)2 * Lu(NO3)3 Hf(NO3)4 TaO(NO3)3 WO2(NO3)2 ReO3NO3 Os Ir3O(NO3)10 Pt Au(NO3)−4 Hg2(NO3)2
    Hg(NO3)2     		TlNO3
    Tl(NO3)3     		Pb(NO3)2 Bi(NO3)3
    BiO(NO3)     		Po(NO3)4 At Rn
    FrNO3 Ra(NO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * La(NO3)3 Ce(NO3)3
    Ce(NO3)4     		Pr(NO3)3 Nd(NO3)3 Pm(NO3)3 Sm(NO3)3 Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy(NO3)3 Ho(NO3)3 Er(NO3)3 Tm(NO3)3 Yb(NO3)3
    ** Ac(NO3)3 Th(NO3)4 PaO(NO3)3 UO2(NO3)2 Np(NO3)4 Pu(NO3)4 Am(NO3)3 Cm(NO3)3 Bk(NO3)3 Cf(NO3)3 Es Fm Md No
    Noble gas compounds
    Helium compounds
    Neon compounds
    Argon compounds
    Krypton compounds
    Xenon compounds
    Xe(0)
    Xe(I)
    Xe(II)
    Xe(IV)
    Xe(VI)
    Xe(VIII)
    Radon compounds
    Rn(II)
    Rn(IV)
    Rn(VI)
    Oganesson compounds
    (predicted)
    Og(0)
    • Og2
    • OgH
    Og(II)
    • OgF2
    • OgCl2
    • OgO
    Og(IV)
    • OgF4
    • OgO2
    • OgTs4
    Og(VI)
    • OgF6
    Hypothetical compound
    Categories:
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