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The host country played with the 7 highest CEV ranking teams which had not yet qualified to the Olympic games. Numbers in brackets denoted the European ranking as of 5 October 2015 except the host which ranked 4th.
The pools composition was announced on 23 October 2015 at the headquarters of CEV, Luxembourg. It followed the Serpentine system according to their European ranking as of 5 October 2015. CEV reserved the right to seed the hosts as head of Pool A regardless of the European ranking.
Match won 3–0 or 3–1: 3 match points for the winner, 0 match points for the loser
Match won 3–2: 2 match points for the winner, 1 match point for the loser