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Indium perchlorate

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Indium perchlorate
Names
Other names Indium triperchlorate, indium(III) perchlorate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.507 Edit this at Wikidata
EC Number
  • 236-874-7
PubChem CID
InChI
  • InChI=1S/3ClHO4.In/c3*2-1(3,4)5;/h3*(H,2,3,4,5);/q;;;+3/p-3Key: TWFKOYFJBHUHCH-UHFFFAOYSA-K
SMILES
  • Cl(=O)(=O)=O.Cl(=O)(=O)=O.Cl(=O)(=O)=O.
Properties
Chemical formula In(ClO4)3
Molar mass 413.17
Appearance colorless crystals
Solubility in water soluble
Hazards
Occupational safety and health (OHS/OSH):
Main hazards Oxidizer
Related compounds
Other anions indium nitrate, indium sulfate
Other cations aluminum perchlorate, gallium perchlorate, thallium perchlorate
Related compounds indium(I) perchlorate, indium chlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Indium perchlorate is the inorganic compound with the chemical formula In(ClO4)3. The compound is an indium salt of perchloric acid.

Synthesis

Dissolving indium hydroxide in perchloric acid:

In(OH)3 + 3HClO4 → In(ClO4)3 + 3H2O

Physical properties

Indium(III) perchlorate forms colorless crystals. It is soluble in water and ethanol.

The compound forms a hydrate In(ClO4)3 • 8H2O, that melts in its own crystallization water at 80 °C.

The octahydrate is easily soluble in ethanol and acetic acid.

References

  1. Burgess, J. (31 October 2007). Inorganic Reaction Mechanisms: Volume 1. Royal Society of Chemistry. p. 110. ISBN 978-1-84755-648-6. Retrieved 15 March 2023.
  2. "Indium Perchlorate". Russian Journal of Physical Chemistry. 48, Part 3. British Library Lending Division: 1611. 1974. Retrieved 15 March 2023.
  3. Eyring, Edward M.; Owen, Jeffrey D. (April 1970). "Kinetics of aqueous indium(III) perchlorate dimerization". The Journal of Physical Chemistry. 74 (9): 1825–1828. doi:10.1021/j100704a001.
  4. "Indium(III) perchlorate hydrate". Sigma Aldrich. Retrieved 15 March 2023.
Indium compounds
Indium(I)
Organoindium(I) compounds
Indium(I,III)
Indium(III)
Organoindium(III) compounds
  • In(C2H5)3
  • In(CH3)3
    • Salts and covalent derivatives of the perchlorate ion
    HClO4 He
    LiClO4 Be(ClO4)2 B(ClO4)−4
    B(ClO4)3     		ROClO3 N(ClO4)3
    NH4ClO4
    NOClO4
    NO2ClO4     		H3OClO4 FClO4 Ne
    NaClO4 Mg(ClO4)2 Al(ClO4)3
    Al(ClO4)−4
    Al(ClO4)2−5
    Al(ClO4)3−6     		Si P S ClO−4
    ClOClO3
    Cl2O7     		Ar
    KClO4 Ca(ClO4)2 Sc(ClO4)3 Ti(ClO4)4 VO(ClO4)3
    VO2(ClO4)     		Cr(ClO4)3 Mn(ClO4)2 Fe(ClO4)2
    Fe(ClO4)3     		Co(ClO4)2
    Co(ClO4)3     		Ni(ClO4)2 Cu(ClO4)2 Zn(ClO4)2 Ga(ClO4)3 Ge As Se BrOClO3 Kr
    RbClO4 Sr(ClO4)2 Y(ClO4)3 Zr(ClO4)4 Nb(ClO4)5 MoO2(ClO4)2 Tc Ru Rh(ClO4)3 Pd(ClO4)2 AgClO4 Cd(ClO4)2 In(ClO4)3 Sn(ClO4)4 Sb(ClO4)3 TeO(ClO4)2 I(OClO3)3 Xe(OClO3)2
    CsClO4 Ba(ClO4)2 * Lu(ClO4)3 Hf(ClO4)4 Ta(ClO4)5
    TaO(ClO4)3
    TaO2ClO4     		WO(ClO4)4 ReO3ClO4 Os Ir Pt Au(ClO4)−4 Hg2(ClO4)2
    Hg(ClO4)2     		Tl(ClO4)
    Tl(ClO4)3     		Pb(ClO4)2 Bi(ClO4)3 Po At Rn
    FrClO4 Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * La(ClO4)3 Ce(ClO4)x Pr(ClO4)3 Nd(ClO4)3 Pm Sm(ClO4)3 Eu(ClO4)3 Gd(ClO4)3 Tb(ClO4)3 Dy(ClO4)3 Ho(ClO4)3 Er(ClO4)3 Tm(ClO4)3 Yb(ClO4)3
    ** Ac Th(ClO4)4 Pa UO2(ClO4)2 Np Pu Am Cm Bk Cf Es Fm Md No
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